Earth System Research Laboratory Halocarbons and Other Atmospheric Trace Gases Old Flask Gas Chromatograph (GC) Measurements
ESRL GMD HATS Old Flask GC; Pre-Otto
The Halocarbons and other Atmospheric Trace Species (HATS) group aims to quantify the atmospheric burden, and the distributions and magnitudes of sources and sinks for nitrous oxide and other halogen containing compounds. They utilize numerous types of platforms, including ground-based stations, towers, ships, aircraft, and balloons to accomplish their mission. HATS measures chlorofluorocarbons (CFCs) at measurement sites spanning the globe. CFCs are non-toxic, non-flammable chemicals that contain carbon, chlorine, and fluorine atoms. CFCs were used as solvents, refrigerants, and aerosol sprays. While inert in the troposphere, they decompose in the stratosphere to release chlorine for destructive reactions with ozone. This process eventually led to the creation of the "Ozone Hole" over the Antarctic. Monitoring the amounts of CFCs and other trace gases is important, both for tracking the growth and recovery of the Ozone Hole, and because many upward trending trace gases are potent and durable greenhouse gases.
Original flask sampling electron capture gas chromatograph ("Pre-Otto") : Air samples collected in flasks at five remote sites, including Barrow, AK (BRW), Mauna Loa, HI (MLO), American Samoa (SMO), South Pole (SPO), Antarctica, and Niwot Ridge, CO (NWR), were analyzed using the HATS group's original electron capture gas chromatograph (GC-ECD) system beginning in 1977. Two additional sites at Alert, Nunavut, Canada (ALT), and Cape Grim, Tasmania (CGO) were added prior to the original Pre-Otto system's retirement in 1995, when it was replaced by a newer, automated system called "Otto". This program was originally set up under the Geophysical Monitoring for Climatic Change (GMCC) division of NOAA's Air Resources Laboratory. Air was collected weekly at these sites in stainless-steel flasks and analyzed for nitrous oxide (N2O), and the chlorofluorocarbons CFC-11 (CCl3F) and CFC-12 (CCl2F2) in the Boulder labs in Colorado.
Through the Big Earth Data Initiative (BEDI), ESRL/GMD has taken their data collection and converted files into NetCDF-4, a self-describing format.
Original flask sampling electron capture gas chromatograph ("Pre-Otto") : Air samples collected in flasks at five remote sites, including Barrow, AK (BRW), Mauna Loa, HI (MLO), American Samoa (SMO), South Pole (SPO), Antarctica, and Niwot Ridge, CO (NWR), were analyzed using the HATS group's original electron capture gas chromatograph (GC-ECD) system beginning in 1977. Two additional sites at Alert, Nunavut, Canada (ALT), and Cape Grim, Tasmania (CGO) were added prior to the original Pre-Otto system's retirement in 1995, when it was replaced by a newer, automated system called "Otto". This program was originally set up under the Geophysical Monitoring for Climatic Change (GMCC) division of NOAA's Air Resources Laboratory. Air was collected weekly at these sites in stainless-steel flasks and analyzed for nitrous oxide (N2O), and the chlorofluorocarbons CFC-11 (CCl3F) and CFC-12 (CCl2F2) in the Boulder labs in Colorado.
Through the Big Earth Data Initiative (BEDI), ESRL/GMD has taken their data collection and converted files into NetCDF-4, a self-describing format.
Dataset Citation
- Cite as: Elkins, James W.; Dutton, Geoff; Nance, David; Bradley Hall; and NOAA ESRL (2017): Earth System Research Laboratory Halocarbons and Other Atmospheric Trace Gases Old Flask Gas Chromatograph (GC) Measurements, Version 1. [indicate subset used]. NOAA National Centers for Environmental Information. doi:10.7289/V5959FT5 [access date].
- Please refer to Credit tab for full citation information.
Dataset Identifiers
- doi:10.7289/V5959FT5
- NCEI DSI 3268_01
- gov.noaa.ncdc:C01553
ISO 19115-2 Metadata
gov.noaa.ncdc:C01553
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Ordering Instructions | Contact NCEI for other distribution options and instructions. |
Distributor |
NOAA National Centers for Environmental Information ncei.info@noaa.gov |
Dataset collaborator | David Nance CIRES Associate Scientist DOC/NOAA/ESRL/GMD > Global Monitoring Division, Earth System Research Laboratory, NOAA, U.S. Department of Commerce (303) 497-7002 david.nance@noaa.gov |
Dataset Point of Contact | Customer Engagement Branch NOAA National Centers for Environmental Information 1-828-271-4800 ncei.orders@noaa.gov |
Time Period | 1977-01-15 to 1995-12-15 (time interval: 1-month) |
Spatial Reference System | urn:ogc:def:crs:EPSG::4326 |
Spatial Bounding Box Coordinates |
West: -180.0
East: 180.0
South: -90.0
North: 90.0
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Edition | Version 1 |
Data Presentation Form | Digital table - digital representation of facts or figures systematically displayed, especially in columns |
Dataset Progress Status | Complete - production of the data has been completed |
Data Update Frequency | Not planned |
Purpose | The general mission of the Halocarbons and other Atmospheric Trace Species group is to quantify the distributions and magnitudes of sources and sinks for atmospheric nitrous oxide (N2O) and halogen containing compounds. |
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Global Change Master Directory (GCMD) Science Keywords
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Global Change Master Directory (GCMD) Data Center Keywords
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Global Change Master Directory (GCMD) Platform Keywords
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Global Change Master Directory (GCMD) Instrument Keywords
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Global Change Master Directory (GCMD) Location Keywords
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Global Change Master Directory (GCMD) Project Keywords
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Global Change Master Directory (GCMD) Horizontal Data Resolution Keywords
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Global Change Master Directory (GCMD) Location Keywords
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Lineage Statement | Air samples were collected in flasks at field sites and transported to NOAA/ESRL/GMD in Boulder, Colorado for analysis by electron capture gas chromatograph (GC-ECD). Data reduction was conducted on a desktop computer. |
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Processing Environment | The GC equipment used to analyze air samples dated to the mid-1970s. A combination of a commercial electronic integrator and manual assessments from hard copy chart traces was used to evaluate chromatographic peak responses. Peak response measures were manually entered into electronic data files for a further reduction in atmospheric mixing ratios. From this point, a series of mostly 1980s and 1990s vintage workstation/desktop scale computers were used to process and reprocess the peak response measures into mixing ratios using a collection of custom developed FORTRAN routines. |
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Last Modified: 2023-06-23
For questions about the information on this page, please email: ncei.info@noaa.gov
For questions about the information on this page, please email: ncei.info@noaa.gov