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Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the KNORR in the South Pacific Ocean from 2005-08-21 to 2005-10-06 (NCEI Accession 0108071)


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            title:  Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the KNORR in the South Pacific Ocean from 2005-08-21 to 2005-10-06 (NCEI Accession 0108071)
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                date:  2013-06-05
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                  Anchor:  DOI 10.3334/cdiac/otg.clivar_aaiw05
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2220 Alex Kozyr
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/5074 Andrew G. Dickson
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 University of California - San Diego; Scripps Institution of Oceanography (SIO)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 University of California - San Diego; Scripps Institution of Oceanography (SIO)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/677 Lynne D. Talley
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/730 University of Rhode Island; Graduate School of Oceanography (GSO)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/5074 Dickson, Andrew G.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 Scripps Institution of Oceanography (SIO)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/677 Talley, Lynne D.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/730 University of Rhode Island; Graduate School of Oceanography (GSO)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/673 Swift, James H.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 University of California - San Diego; Scripps Institution of Oceanography (SIO)
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        abstract:  This dataset includes chemical, discrete sample, physical and profile data collected from KNORR in the South Pacific Ocean from 2005-08-21 to 2005-10-06 and retrieved during cruise CLIVAR_AAIW05. These data include ALKALINITY, CHLOROFLUOROCARBON-11 (CFC-11), CHLOROFLUOROCARBON-113 (CFC-113), CHLOROFLUOROCARBON-12 (CFC-12), Carbon tetrachloride (CCL4), DISSOLVED INORGANIC CARBON, DISSOLVED OXYGEN, HYDROSTATIC PRESSURE, NITRATE, NITRITE, PHOSPHATE, Partial pressure (or fugacity) of carbon dioxide, SALINITY, SILICATE, WATER TEMPERATURE and pH. The instruments used to collect these data include Alkalinity titrator, CTD, Coulometer for DIC measurement and bottle. These data were collected by Andrew Dickson, Lynne Talley and James Swift of Scripps Institution of Oceanography as part of the CLIVAR_AAIW05 data set. The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
        purpose:  This dataset is available to the public for a wide variety of uses including scientific research and analysis.
        credit:  Funding Information: NSF
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/671 Carbon tetrachloride (CCL4)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/588 DISSOLVED INORGANIC CARBON (DIC)
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/fa0ec8a7-ebed-4f2d-834b-1fa6a1c2e0ed OCEAN > PACIFIC OCEAN > SOUTH PACIFIC OCEAN
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            keyword:  Pacific Ocean
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            otherConstraints:  Cite as: Dickson, Andrew G.; Talley, Lynne D.; Swift, James H.; Chereskin, Teresa K.; Fine, Rana A. (2013). Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the KNORR in the South Pacific Ocean from 2005-08-21 to 2005-10-06 (NCEI Accession 0108071). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.clivar_aaiw05. Accessed [date].
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                westBoundLongitude:  -103.0888
                eastBoundLongitude:  -72.6826
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        supplementalInformation:  These data were acquired by NODC from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NODC. NODC cannot verify the accuracy or availability of the data provider's citation information, which is maintained by CDIAC.
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) dataset
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0108071 v1.1 was published.
                dateTime:
                  DateTime:  2013-06-05T20:10:07Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0108071 v1.1
                        date:  (CI_Date)
                            date: (inapplicable)
                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0108071/1.1
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0108071 v1.1
                                    description:  published 2013-06-05T20:10:07Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) dataset
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: A control chart was prepared using the duplicate data as described in SOP 22 of the DOE handbook (Figure 4). The average non-absolute difference (2nd - 1st in the order of analysis) was 0.38 μmol kg-1 and the standard deviation was 1.2 μmol kg-1. The average value is statistically distinguishable from zero, where zero is the ideal result that would indicate all sources of error were random or independent of both time and the amount of carbon titrated within a given cell. It is thought that this error is related to the chemical evolution of the cell solutions with repeated titrations. However, since the exact nature of these cells’ chemistry is not well-understood, no correction was made to account for this observation.; Standardization description: A total of 2,935 CT analyses were made including: 1. 189 measurements of Certified Reference Materials (CRM Batch 71, CT 2032.85 ± 0.40 μmol kg-1). 2. 196 sets of duplicate measurements made on separate seawater samples collected from the same Niskin. 3. 86 measurements made on four separate batches of a reference material that were prepared at sea. 4. 25 rejected measurements of samples with known errors. 5. 2439 measurements of sample CT that are presented with quality control codes.; CRM batch number: 71.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: potentiometric titration; Cell type (open or closed): Open; Curve fitting method: Potentiometric, open-cell titration by coulometrically analyzed hydrochloric acid.; Uncertainty: The mean and standard deviation for all CRM analyses are 2056.3 ± 3.0 μmol/kg; Method reference: Dickson, A. G., Afghan, J.D., Anderson, G.C., 2003. Reference Materials for Oceanic CO2 analysis: a Method for the Certification of Total Alkalinity. Marine Chemistry 80, 185-197.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC113; Abbreviation: CFC113; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-113 (CFC-113); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CCL4; Abbreviation: CCL4; Unit: PMOL/KG; Controlled vocabulary name: Carbon tetrachloride (CCL4); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ .
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) repository
            levelDescription:  (MD_ScopeDescription)
                other:  NOAA National Centers for Environmental Information
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
                dateTime:
                  DateTime:  2015-04-22T00:00:00
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  bottle
            type:  bottle
            description:  any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  coulometer for DIC measurement
            type:  coulometer for DIC measurement
            description:  measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  CTD
            type:  CTD
            description:  Conductivity-Temperature-Depth probe
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  titrator
            type:  titrator
            description:  titrator
        platform:  (MI_Platform)
            identifier:  (MD_Identifier)
                code:  R/V Knorr
            description:  Title: R/V Flag: United States of America Vessel Type: Research Vessel (Oceanographic) DOB: 1970 IMO: 7738618 MMSI: 367246000
            instrument: (missing)