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Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship RONALD H. BROWN in the North Atlantic Ocean and South Atlantic Ocean from 2010-03-08 to 2010-04-17 (NCEI Accession 0108156)


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            title:  Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship RONALD H. BROWN in the North Atlantic Ocean and South Atlantic Ocean from 2010-03-08 to 2010-04-17 (NCEI Accession 0108156)
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                date:  2013-06-07
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                  Anchor:  DOI 10.3334/cdiac/otg.clivar_a13.5_2010
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2220 Alex Kozyr
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/970 Richard A. Feely
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2530 Rik Wanninkhof
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 University of California - San Diego; Scripps Institution of Oceanography (SIO)
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                  Anchor:  https://orcid.org/0000-0003-3245-3568 Feely, Richard A.
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                  Anchor:  https://orcid.org/0000-0001-9275-3445 Hansell, Dennis A.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1576 University of Miami
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2214 Key, Robert M.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/268 US DOC; NOAA; OAR; Atlantic Oceanographic and Meteorological Laboratory (AOML)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/717 University of Miami Rosenstiel School of Marine and Atmospheric Science (RSMAS)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 University of California - San Diego; Scripps Institution of Oceanography (SIO)
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        abstract:  This dataset includes chemical, discrete sample, physical and profile data collected from NOAA Ship RONALD H. BROWN in the North Atlantic Ocean and South Atlantic Ocean from 2010-03-08 to 2010-04-17. These data include CHLOROFLUOROCARBON-11 (CFC-11), CHLOROFLUOROCARBON-12 (CFC-12), Carbon tetrachloride (CCL4), DELTA CARBON-13, DELTA CARBON-14, DELTA HELIUM-3, DISSOLVED INORGANIC CARBON (DIC), DISSOLVED ORGANIC CARBON, DISSOLVED OXYGEN, HELIUM, HYDROSTATIC PRESSURE, NITRATE, NITRITE, Partial pressure (or fugacity) of carbon dioxide - water, Potential temperature (theta), SALINITY, SULFUR HEXAFLUORIDE (SF6), TOTAL ALKALINITY (TA), Total Dissolved Nitrogen (TDN), Tritium (Hydrogen isotope), WATER TEMPERATURE, pH, phosphate and silicate. The instruments used to collect these data include Alkalinity titrator, CTD, Carbon dioxide (CO2) gas analyzer, Coulometer for DIC measurement, Flask with closed headspace for discrete carbon dioxide (CO2) measurement, bottle and spectrophotometer. These data were collected by Dennis Hansell of Rosenstiel School of Marine and Atmospheric Science, Rik Wanninkhof of NOAA Atlantic Oceanographic and Meteorological Laboratory, Richard A. Feely of US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory and Andrew Dickson of University of California - San Diego; Scripps Institution of Oceanography as part of the CLIVAR_A13.5_2010 data set. CDIAC associated the following cruise ID(s) with this data set: CLIVAR_A13.5_2010 and RB_07-05 The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
        purpose:  This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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                    date:  2017-02-21
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/671 Carbon tetrachloride (CCL4)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/493 CHLOROFLUOROCARBON-11 (CFC-11)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/494 CHLOROFLUOROCARBON-12 (CFC-12)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/579 DELTA CARBON-13
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/578 DELTA CARBON-14
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/577 DELTA HELIUM-3
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/588 DISSOLVED INORGANIC CARBON (DIC)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/114 DISSOLVED ORGANIC CARBON
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/116 DISSOLVED OXYGEN
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/157 HELIUM
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/589 HYDROSTATIC PRESSURE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/223 NITRATE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/226 NITRITE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/70 partial pressure of carbon dioxide - water
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/257 pH
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/263 phosphate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/572 Potential temperature (theta)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/307 SALINITY
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/333 silicate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/618 sulfur hexafluoride (SF6)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/5 total alkalinity
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/668 Total Dissolved Nitrogen (TDN)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/392 Tritium (Hydrogen isotope)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/373 WATER TEMPERATURE
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                date: (inapplicable)
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                date: (inapplicable)
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            keyword:  oceanography
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                    date:  2012-09-15
                    dateType:  (CI_DateTypeCode) publication
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                            name:  GCMD Keyword Forum Page
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            type:  (MD_KeywordTypeCode) project
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                    dateType:  (CI_DateTypeCode) revision
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                            administrativeArea:  MD
                        onlineResource:  (CI_OnlineResource)
                            linkage: https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords
                            protocol:  HTTPS
                            name:  GCMD Keyword Forum Page
                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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            keyword:  DIC
            keyword:  DOC
            keyword:  FCO2TMP
            keyword:  NITRAT
            keyword:  NITRIT
            keyword:  OXYGEN
            keyword:  PHSPHT
            keyword:  PH_TMP
            keyword:  SALNTY
            keyword:  SF6
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            keyword:  fCO2
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                title:  Provider Variable Abbreviations
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                            name:  GCMD Keyword Forum Page
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                            name:  GCMD Keyword Forum Page
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              Anchor:  https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/33RO Ronald H. Brown (call sign: WTEC, ICES code: 33RO, 1997)
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                title:  ICES/SeaDataNet Ship Codes
                date: (inapplicable)
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                    dateType:  (CI_DateTypeCode) revision
                edition:  17
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                            protocol:  HTTPS
                            name:  GCMD Keyword Forum Page
                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
                            function:  (CI_OnLineFunctionCode) information
                    role:  (CI_RoleCode) custodian
        descriptiveKeywords:  (MD_Keywords)
            keyword:  Atlantic Ocean
            type:  (MD_KeywordTypeCode) place
            thesaurusName:  (CI_Citation)
                title:  Provider Geographic Names
                date: (inapplicable)
        resourceConstraints:  (MD_Constraints)
            useLimitation:  accessLevel: Public
        resourceConstraints:  (MD_LegalConstraints)
            useConstraints:  (MD_RestrictionCode) otherRestrictions
            otherConstraints:  Cite as: Bullister, John L.; Feely, Richard A.; Wanninkhof, Rik; Dickson, Andrew G.; Hansell, Dennis A.; Key, Robert M. (2013). Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship RONALD H. BROWN in the North Atlantic Ocean and South Atlantic Ocean from 2010-03-08 to 2010-04-17 (NCEI Accession 0108156). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.clivar_a13.5_2010. Accessed [date].
        resourceConstraints:  (MD_LegalConstraints)
            useLimitation:  Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.
        resourceConstraints:  (MD_LegalConstraints)
            accessConstraints:  (MD_RestrictionCode) otherRestrictions
            otherConstraints:  Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
        aggregationInfo:  (MD_AggregateInformation)
            aggregateDataSetName:  (CI_Citation)
                title:  Bullister, J., R. Feely, R. Wanninkhof, A. Dickson, D. Hansell, and R. Key (2010). Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Ronald H. Brown Cruise in the Atlantic Ocean on CLIVAR Repeat Hydrography Section A13.5 (Mar. 08 - Apr. 17, 2010). Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee, CLIVAR_A13.5_2010.
                date:  (CI_Date)
                    date:  2010
                    dateType:  (CI_DateTypeCode) publication
                identifier:  (MD_Identifier)
                    code:  CLIVAR_A13.5_2010
                citedResponsibleParty:  (CI_ResponsibleParty)
                    individualName:  Bullister, J., R. Feely, R. Wanninkhof, A. Dickson, D. Hansell, and R. Key
                    role:  (CI_RoleCode) author
                citedResponsibleParty:  (CI_ResponsibleParty)
                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
                    contactInfo:  (CI_Contact)
                        onlineResource:  (CI_OnlineResource)
                            linkage: http://cdiac.ornl.gov
                            protocol:  HTTP
                            name:  Carbon Dioxide Information Analysis Center website
                            description:  Institution web page
                            function:  (CI_OnLineFunctionCode) information
                    role:  (CI_RoleCode) publisher
                series:  (CI_Series)
                    name:  Ocean CO2
                otherCitationDetails:  [retrieved from http://cdiac.ornl.gov/ftp/oceans/CLIVAR/A13.5_2010.data/]
            associationType:  (DS_AssociationTypeCode) crossReference
        aggregationInfo:  (MD_AggregateInformation)
            aggregateDataSetName:  (CI_Citation)
                title:  NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
                date:  (CI_Date)
                    date:  2022-04
                    dateType:  (CI_DateTypeCode) publication
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                    positionName: (unknown)
                    contactInfo:  (CI_Contact)
                        onlineResource:  (CI_OnlineResource)
                            linkage: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
                            protocol:  HTTPS
                            name: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
                            description:  OCADS website
                            function:  (CI_OnLineFunctionCode) information
                    role: (unknown)
                citedResponsibleParty:  (CI_ResponsibleParty)
                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
                    role:  (CI_RoleCode) author
                citedResponsibleParty:  (CI_ResponsibleParty)
                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
                    role:  (CI_RoleCode) publisher
                presentationForm:  (CI_PresentationFormCode) documentDigital
                otherCitationDetails:  [accessed 2024-02-08]
            associationType:  (DS_AssociationTypeCode) crossReference
            initiativeType:  (DS_InitiativeTypeCode) program
        language:
          LanguageCode:  eng; USA
        characterSet:  (MD_CharacterSetCode) utf8
        topicCategory:  (MD_TopicCategoryCode) environment
        topicCategory:  (MD_TopicCategoryCode) oceans
        extent:  (EX_Extent)
            geographicElement:  (EX_GeographicBoundingBox)
                westBoundLongitude:  -3.0018
                eastBoundLongitude:  1.833
                southBoundLatitude:  -54.0007
                northBoundLatitude:  4.7108
            temporalElement:  (EX_TemporalExtent)
                extent:
                  TimePeriod:
                    beginPosition:  2010-03-08
                    endPosition:  2010-04-17
        supplementalInformation:  These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI. In this accession, NCEI has archived multiple versions of these data. The latest (and best) version of these data has the largest version number.
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    distributionInfo:  (MD_Distribution)
        distributor:  (MD_Distributor)
            distributorContact:  (CI_ResponsibleParty)
                organisationName:
                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
                contactInfo:  (CI_Contact)
                    phone:  (CI_Telephone)
                        voice:  +1-301-713-3277
                    address:  (CI_Address)
                        electronicMailAddress:  NCEI.Info@noaa.gov
                role:  (CI_RoleCode) pointOfContact
            distributionOrderProcess:  (MD_StandardOrderProcess)
                fees:  In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
                orderingInstructions:  Contact NCEI for other distribution options and instructions.
            distributorFormat:  (MD_Format)
                name:  CSV
                version: (unknown)
            distributorTransferOptions:  (MD_DigitalTransferOptions)
                transferSize:
                  Real:  6.14
                onLine:  (CI_OnlineResource)
                    linkage: https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0108156.html
                    protocol:  HTTPS
                    applicationProfile:  Web browser
                    name:  Project Metadata
                    description:  Navigate directly to the URL for a descriptive web page with download links.
                    function:  (CI_OnLineFunctionCode) information
                onLine:  (CI_OnlineResource)
                    linkage: https://doi.org/10.3334/cdiac/otg.clivar_a13.5_2010
                    protocol:  HTTPS
                    applicationProfile:  Web browser
                    name:  NCEI Dataset Landing Page
                    description:  Navigate directly to the URL for a descriptive web page with download links.
                    function:  (CI_OnLineFunctionCode) information
                onLine:  (CI_OnlineResource)
                    linkage: https://www.ncei.noaa.gov/archive/accession/oas/108156
                    protocol:  HTTPS
                    applicationProfile:  Web browser
                    name:  Descriptive Information
                    description:  Navigate directly to the URL for a descriptive web page with download links.
                    function:  (CI_OnLineFunctionCode) information
                onLine:  (CI_OnlineResource)
                    linkage: https://www.ncei.noaa.gov/archive/accession/download/108156
                    protocol:  HTTPS
                    applicationProfile:  Web browser
                    name:  HTTPS
                    description:  Navigate directly to the URL for data access and direct download.
                    function:  (CI_OnLineFunctionCode) download
                onLine:  (CI_OnlineResource)
                    linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0057/0108156/
                    protocol:  FTP
                    applicationProfile:  Any FTP client
                    name:  FTP
                    description:  These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
                    function:  (CI_OnLineFunctionCode) download
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) dataset
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0108156 v1.1 was published.
                dateTime:
                  DateTime:  2013-06-07T19:44:09Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0108156 v1.1
                        date:  (CI_Date)
                            date: (inapplicable)
                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0108156/1.1
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0108156 v1.1
                                    description:  published 2013-06-07T19:44:09Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0108156 was revised and v2.2 was published.
                rationale:  Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
                dateTime:
                  DateTime:  2017-02-21T14:55:17Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0108156 v2.2
                        date:  (CI_Date)
                            date: (inapplicable)
                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0108156/2.2
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0108156 v2.2
                                    description:  published 2017-02-21T14:55:17Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) dataset
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: The precision is displayed by the greater than 300 replicate samples drawn. The absolute average difference from the mean of these replicates is less than 0.75 μmol/kg. No significant systematic differences were noted.; Standardization description: The coulometers were each calibrated by injecting aliquots of pure CO2 (99.995%) by means of an 8-port valve outfitted with two sample loops. The instruments were calibrated at the beginning, middle, and end of each station with a set of the gas loop injections.; CRM batch number: Batch 98.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Single point titration; Cell type (open or closed): Open; Curve fitting method: Total alkalinity measurements were made using an open-cell, two-stage, potentiometric titration procedure similar to that used to certify reference materials for total alkalinity (see Dickson et al., 2003), except that samples were not weighed into the titration vessel but instead 99.9 mL was dispensed from a Dosimat using a 50 mL burette.; Uncertainty: The at-sea repeatability of the method was estimated by analyzing duplicate samples, collected on each cast. These results were used to estimate a standard deviation using the standard expression (DOE, 1994, SOP 23). The repeatability was 1.38 μmol/kg, based on 237 pairs of analyses. In addition, analyses were made of the alkalinity of CO2 reference material. These analyses were carried out 253 times through out the cruise and at most stations.; Method reference: Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp..
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: pH; Abbreviation: pH; pH scale: total hydrogen ion scale; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25C; Detailed sampling and analyzing information: pH values were measured spectrophotometrically, using the constants of Liu et al. (2011) at a temperature ranging between 17 and 20 deg. C. These values are adjusted to counter errors created by the use of constants determined for purified m-cresol dye for measurements made with unpurified (Acros Organics) dye. The applied adjustment is a pH dependent offset estimated by fitting a 2nd order polynomial to the data in figure 2a in the article by Liu et al. (2011). The likely uncertainties on these measurements are explored in detail in Carter et al. (conditionally accepted, 2013). These values have been further adjusted to the reported values at 25 C using CO2SYS (van Hueven et al., 2009) with the carbonate constants given by Dickson and Millero (1987). For the ~10 samples lacking sufficient carbonate constraints for this calculation, the mean value of the missing data from the samples above and below the sample in the water column were used. This data is estimated to have a precision and accuracy uncertainty of 0.0006 and 0.006 pH units respectively.; Uncertainty: Precision estimate: +/-0.0006. Accuracy estimate: +/-0.006..
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: pCO2 (fCO2) discrete; Abbreviation: fCO2; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Storage method: NA; Seawater volume: 500mL; Headspace volume: 50mL; Temperature of measurement: 20C; Detailed sampling and analyzing information: The discrete pCO2 system is patterned after the instrument described in Chipman et al. (1991) and is discussed in detail in Wanninkhof and Thoning (1993) and Chen et al. (1995). The major difference between the two systems is that the Wanninkhof and current instrument uses a LI-COR model 6262 non-dispersive infrared analyzer, while the Chipman instrument utilizes a gas chromatograph with a flame ionization detector.; Sample replicate information: There were 183 pairs of duplicate samples drawn from Niskins on 101 stations. The average relative difference between all the pairs was 0.250 % (+/- 0.287 %). If the four relative differences above 1% are excluded (~95% confidence interval), the average relative difference was 0.220 % (+/- 0.209 %).; Temperature correction method: Small adjustments to 20.00 C were performed using the temperature coefficients of the carbonate dissociation constants.; Uncertainty: NA; Method reference: Chipman, D. W., T. Takahashi, D. Breger, and S.C. Sutherland (1991), Investigation of carbon dioxide in the South Atlantic and Northern Weddell areas (WOCE section A-12 and A-21) during the METEOR expedition 11/5 Jan.-March 1990, LDGO of Columbia University, Palisades. Wanninkhof, R., and K. Thoning (1993), Measurement of fugacity of CO2 in surface water using continuous and discrete sampling methods, Mar. Chem., 44, 189-205. Chen, H., R. Wanninkhof, R. A. Feely, and D. Greeley (1995), Measurement of fugacity of carbon dioxide in sub-surface water: an evaluation of a method based on infrared analysis, NOAA technical report ERL AOML-85, 52 pp, NOAA/AOML..
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SF6; Abbreviation: SF6; Unit: FMOL/KG; Controlled vocabulary name: Sulfur Hexaflouride (SF6); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CCL4; Abbreviation: CCL4; Unit: PMOL/KG; Controlled vocabulary name: Carbon tetrachloride (CCL4); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: FCO2; Abbreviation: FCO2; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: FCO2TMP; Abbreviation: FCO2TMP; Unit: DEG_C; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH; Abbreviation: PH; Unit: TOT@25C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: DOC; Abbreviation: DOC; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED ORGANIC CARBON; In-situ / Manipulation / Response variable: in-situ .
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) repository
            levelDescription:  (MD_ScopeDescription)
                other:  NOAA National Centers for Environmental Information
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
                dateTime:
                  DateTime:  2015-04-22T00:00:00
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        maintenanceNote:  NCEI Accession 0108156 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  bottle
            type:  bottle
            description:  any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  carbon dioxide (CO2) gas analyzer
            type:  carbon dioxide (CO2) gas analyzer
            description:  measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  coulometer for DIC measurement
            type:  coulometer for DIC measurement
            description:  measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  CTD
            type:  CTD
            description:  Conductivity-Temperature-Depth probe
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  flask with closed headspace for discrete CO2 measurement
            type:  flask with closed headspace for discrete CO2 measurement
            description:  discrete carbon dioxide (CO2) measurement
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  spectrophotometer
            type:  spectrophotometer
            description:  spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  titrator
            type:  titrator
            description:  titrator
        platform:  (MI_Platform)
            identifier:  (MD_Identifier)
                code:  NOAA Ship Ronald H. Brown
            description:  Updated information from ICES for UNITED STATES platform Ronald H. Brown Flag : UNITED STATES - US (ISO Country Code) Call Sign : WTEC Title : NOAA Ship Platform Class : Research vessel IMO : 9105786 Pennant : R 104 Commissioned Date : 1997-07-19 Current Length : 83.5 Built : 1997 Information Source : http://www.moc.noaa.gov/rb/index.html (URL) Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=277516 *General Comments:* Name RESEARCHER II planned during build was never used.
            instrument: (missing)