Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from ATLANTIS in the Caribbean Sea and North Atlantic Ocean from 2012-03-24 to 2012-04-17 (NCEI Accession 0109915)
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title: Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from ATLANTIS in the Caribbean Sea and North Atlantic Ocean from 2012-03-24 to 2012-04-17 (NCEI Accession 0109915)
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abstract: This dataset includes discrete sample and profile data collected from ATLANTIS in the Caribbean Sea and North Atlantic Ocean from 2012-03-24 to 2012-04-17 and retrieved during cruise CLIVAR_A22_2012. These data include CHLOROFLUOROCARBON-11 (CFC-11), CHLOROFLUOROCARBON-113 (CFC-113), CHLOROFLUOROCARBON-12 (CFC-12), Carbon tetrachloride (CCL4), DELTA CARBON-13, DELTA CARBON-14, DELTA HELIUM-3, DISSOLVED INORGANIC CARBON (DIC), DISSOLVED ORGANIC CARBON, DISSOLVED OXYGEN, HELIUM, HYDROSTATIC PRESSURE, NEON, NITRATE, NITRITE, Potential temperature (theta), SALINITY, SULFUR HEXAFLUORIDE (SF6), TOTAL ALKALINITY (TA), Total Dissolved Nitrogen (TDN), Tritium (Hydrogen isotope), WATER TEMPERATURE, pH, phosphate and silicate. The instruments used to collect these data include Alkalinity titrator, CTD, Coulometer for DIC measurement, bottle and spectrophotometer. These data were collected by Dennis Hansell of Rosenstiel School of Marine and Atmospheric Science, Rik Wanninkhof of NOAA Atlantic Oceanographic and Meteorological Laboratory and Richard A. Feely of US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory as part of the CLIVAR_A22_2012 data set. The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0109915/3.3
protocol: HTTPS
name: NCEI Accession 0109915 v3.3
description: published 2016-02-21T19:05:40Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: Greater than 10% of these samples were taken as replicates as a check of our precision. These replicate samples were typically taken from the surface, oxygen minimum, and bottom bottles. The replicate samples were interspersed throughout the station analysis for quality assurance and integrity of the coulometer cell solutions and no systematic differences between the replicates were observed. The absolute average difference from the mean of these replicates is 0.8 μmol/kg.; Standardization description: Secondary standards were run throughout the cruise (at least one per station) on each analytical system. These standards are Certified Reference Materials (CRMs), consisting of poisoned, filtered, and UV irradiated seawater supplied by Dr. A. Dickson of Scripps Institution of Oceanography (SIO). Their accuracy is determined manometrically on land in San Diego. DIC data reported to the database have been corrected to the batch 117 CRM value. The reported CRM value for this batch is 2009.99 μmol/kg. The average measured values (in μmol/kg during this cruise) were 2010.36 for PMEL-1 and 2010.47 for PMEL-2.; CRM batch number: Batch 117.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Single point titration, open cell.; Cell type (open or closed): Open; Curve fitting method: Total alkalinity measurements were made using an open-cell, two-stage, potentiometric titration procedure similar to that used to certify reference materials for total alkalinity (see Dickson et al., 2003), except that samples were not weighed into the titration vessel but instead 99.9 mL was dispensed from a Dosimat using a 50 mL burette.; Method reference: Dickson, A.G., 1981. An exact definition of total alkalinity and a procedure for the estimation of alkalinity and total CO2 from titration data, Deep-Sea Res., 28, 609-623. Dickson, A.G., 1990. Thermodynamics of the dissociation of boric acid in synthetic seawater from 273.15 to 318.15K, Deep-Sea Res., 37,755-766. Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007.Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp. (SOP 3b, Determination of total alkalinity in sea water using an open cell titration). Millero F. J., Zhang, J. Z., Lee, K., and Campbell, D. M., 1993.Titration alkalinity of seawater, Marine Chemistry, 44, 153-165. Millero, F.J., T. B. Graham, F. Huang, H. Bustos-Serrano, D. Pierrot, 2006. Dissociation constants of carbonic acid in seawater as a function of salinity and temperature, Marine Chemistry.100, 80-94, 2006..
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH; pH scale: total hydrogen ion scale; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25C; Detailed sampling and analyzing information: pH on the total scale was measured using an Agilent 8453 spectrophotometer according to the methods outlined by Clayton and Byrne (1993). A Thermo NESLAB RTE-7 water bath maintained spectrophotometric cell temperature at 25.0C..
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC113; Abbreviation: CFC113; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-113 (CFC-113); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SF6; Abbreviation: SF6; Unit: FMOL/KG; Controlled vocabulary name: Sulfur Hexaflouride (SF6); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CCL4; Abbreviation: CCL4; Unit: PMOL/KG; Controlled vocabulary name: Carbon tetrachloride (CCL4); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_TOT; Abbreviation: PH_TOT; Unit: @25C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DOC; Abbreviation: DOC; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED ORGANIC CARBON; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TDN; Abbreviation: TDN; Unit: UMOL/KG; Controlled vocabulary name: Total Dissolved Nitrogen (TDN); In-situ / Manipulation / Response variable: in-situ .
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) repository
levelDescription: (MD_ScopeDescription)
other: NOAA National Centers for Environmental Information
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
dateTime:
DateTime: 2015-04-22T00:00:00
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0109915 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: coulometer for DIC measurement
type: coulometer for DIC measurement
description: measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: spectrophotometer
type: spectrophotometer
description: spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: titrator
type: titrator
description: titrator
platform: (MI_Platform)
identifier: (MD_Identifier)
code: R/V Atlantis
description: Flag: United States of America Vessel Type: Research Vessel (Oceanographic) DOB: Mar 1997 IMO: 9105798 AS OF 3/3/1997 - WHOI https://www.whoi.edu/what-we-do/explore/ships/ships-atlantis/
instrument: (missing)
