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Carbon dioxide, hydrographic, and chemical data obtained during the R/V Nathaniel B. Palmer cruise in the Southern Ocean on CLIVAR Repeat Hydrography Section S04P from 2011-02-19 to 2011-04-23 (NCEI Accession 0109933)


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            title:  Carbon dioxide, hydrographic, and chemical data obtained during the R/V Nathaniel B. Palmer cruise in the Southern Ocean on CLIVAR Repeat Hydrography Section S04P from 2011-02-19 to 2011-04-23 (NCEI Accession 0109933)
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                date:  2013-07-03
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                  Anchor:  DOI 10.3334/cdiac/otg.clivar_s04p_2011
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2220 Alex Kozyr
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/970 Richard A. Feely
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/968 Frank J. Millero
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2213 Christopher L. Sabine
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/5074 Dickson, Andrew G.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/968 Millero, Frank J.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/717 University of Miami Rosenstiel School of Marine and Atmospheric Science (RSMAS)
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                  Anchor:  https://orcid.org/0000-0001-9275-3445 Hansell, Dennis A.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1576 University of Miami
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/983 University of California - San Diego; Scripps Institution of Oceanography (SIO)
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        abstract:  This dataset includes discrete sample data collected from NATHANIEL B. PALMER in the Southern Oceans from 2011-02-19 to 2011-04-23. These data include CHLOROFLUOROCARBON-11 (CFC-11), CHLOROFLUOROCARBON-113 (CFC-113), CHLOROFLUOROCARBON-12 (CFC-12), DELTA CARBON-13, DELTA CARBON-14, DELTA HELIUM-3, DISSOLVED INORGANIC CARBON (DIC), DISSOLVED ORGANIC CARBON, DISSOLVED OXYGEN, HELIUM, HYDROSTATIC PRESSURE, NEON, NITRATE, NITRITE, Partial pressure (or fugacity) of carbon dioxide - water, Potential temperature (theta), SALINITY, SEA SURFACE TEMPERATURE, SULFUR HEXAFLUORIDE (SF6), TOTAL ALKALINITY (TA), Total Dissolved Nitrogen (TDN), Tritium (Hydrogen isotope), WATER TEMPERATURE, pH, phosphate and silicate. The instruments used to collect these data include Alkalinity titrator, CTD, Coulometer for DIC measurement, bottle and spectrophotometer. These data were collected by Frank J. Millero and Dennis Hansell of Rosenstiel School of Marine and Atmospheric Science, Richard A. Feely and Christopher Sabine of US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory and Andrew Dickson of University of California - San Diego; Scripps Institution of Oceanography as part of the CLIVAR_S04P_2011 data set. The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
        purpose:  This dataset is available to the public for a wide variety of uses including scientific research and analysis.
        credit:  Funding Information: NSF
        credit:  Funding Information: NSF
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/493 CHLOROFLUOROCARBON-11 (CFC-11)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/585 CHLOROFLUOROCARBON-113 (CFC-113)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/494 CHLOROFLUOROCARBON-12 (CFC-12)
            keyword:
              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/579 DELTA CARBON-13
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/578 DELTA CARBON-14
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/577 DELTA HELIUM-3
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/588 DISSOLVED INORGANIC CARBON (DIC)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/114 DISSOLVED ORGANIC CARBON
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/116 DISSOLVED OXYGEN
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/157 HELIUM
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/589 HYDROSTATIC PRESSURE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/581 NEON
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/223 NITRATE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/226 NITRITE
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            keyword:
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            keyword:
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            keyword:
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/platform/details/3623 RV Nathaniel B. Palmer
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                title:  WMO_CategoryCode
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                    date:  2012-09-15
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                            protocol:  HTTPS
                            name:  GCMD Keyword Forum Page
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                date: (inapplicable)
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/b971f45d-3a45-4ef2-99df-d6b88bbc7cc3 CLIVAR > Climate Variability
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                    dateType:  (CI_DateTypeCode) revision
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                            administrativeArea:  MD
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                            protocol:  HTTPS
                            name:  GCMD Keyword Forum Page
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                title:  Ocean Acidification Search Keywords
                date: (inapplicable)
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            type:  (MD_KeywordTypeCode) project
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/4fde380a-38c5-4d46-bc80-4f2515a43983 EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > NITRATE
            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/941410da-0b7f-4ec6-a718-212194ced13f EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > NITRITE
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            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/d3055f47-258e-4556-a885-54cd1fff4680 EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > ORGANIC CARBON
            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/90aa8838-79bd-4b28-b518-8217e863c385 EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > OXYGEN
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/bd24a9a9-7d52-4c29-b2a0-6cefd216ae78 EARTH SCIENCE > OCEANS > OCEAN TEMPERATURE > SEA SURFACE TEMPERATURE
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            keyword:  CFC-11
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            keyword:  CTDOXY
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            keyword:  DOC
            keyword:  NITRAT
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            keyword:  OXYGEN
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            keyword:  SALNTY
            keyword:  SF6
            keyword:  SILCAT
            keyword:  TA
            keyword:  TCARBN
            keyword:  TDN
            keyword:  TRITER
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                            linkage: https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords
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                            name:  GCMD Keyword Forum Page
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                date: (inapplicable)
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/b791f381-1c1c-4958-bc7d-b72a15da1174 OCEAN > SOUTHERN OCEAN
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                title:  Global Change Master Directory (GCMD) Location Keywords
                date:  (CI_Date)
                    date:  2023
                    dateType:  (CI_DateTypeCode) revision
                edition:  17
                citedResponsibleParty:  (CI_ResponsibleParty)
                    organisationName:  Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)
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                            city:  Greenbelt
                            administrativeArea:  MD
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                            linkage: https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords
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                            name:  GCMD Keyword Forum Page
                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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        descriptiveKeywords:  (MD_Keywords)
            keyword:  Southern Ocean
            type:  (MD_KeywordTypeCode) place
            thesaurusName:  (CI_Citation)
                title:  Provider Geographic Names
                date: (inapplicable)
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            useLimitation:  accessLevel: Public
        resourceConstraints:  (MD_LegalConstraints)
            useConstraints:  (MD_RestrictionCode) otherRestrictions
            otherConstraints:  Cite as: Sabine, Christopher L.; Feely, Richard A.; Wanninkhof, Rik; Dickson, Andrew G.; Millero, Frank J.; Hansell, Dennis A.; Swift, James H.; McNichol, Ann; Key, Robert M. (2013). Carbon dioxide, hydrographic, and chemical data obtained during the R/V Nathaniel B. Palmer cruise in the Southern Ocean on CLIVAR Repeat Hydrography Section S04P from 2011-02-19 to 2011-04-23 (NCEI Accession 0109933). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.clivar_s04p_2011. Accessed [date].
        resourceConstraints:  (MD_LegalConstraints)
            useLimitation:  Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.
        resourceConstraints:  (MD_LegalConstraints)
            accessConstraints:  (MD_RestrictionCode) otherRestrictions
            otherConstraints:  Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
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                title:  Sabine, C., R. Feely, R. Wanninkhof, A. Dickson, F. MIllero, D. Hansell, J. Swift, A. McNichol and R. Key (2012). Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Nathaniel B. Palmer Cruise in the Southern Ocean on CLIVAR Repeat Hydrography Section S04P (Feb. 19 - Apr. 23, 2011). Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee, CLIVAR_S04P_2011.
                date:  (CI_Date)
                    date:  2012
                    dateType:  (CI_DateTypeCode) publication
                identifier:  (MD_Identifier)
                    code:  CLIVAR_S04P_2011
                citedResponsibleParty:  (CI_ResponsibleParty)
                    individualName:  Sabine, C., R. Feely, R. Wanninkhof, A. Dickson, F. MIllero, D. Hansell, J. Swift, A. McNichol and R. Key
                    role:  (CI_RoleCode) author
                citedResponsibleParty:  (CI_ResponsibleParty)
                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
                    contactInfo:  (CI_Contact)
                        onlineResource:  (CI_OnlineResource)
                            linkage: http://cdiac.ornl.gov
                            protocol:  HTTP
                            name:  Carbon Dioxide Information Analysis Center website
                            description:  Institution web page
                            function:  (CI_OnLineFunctionCode) information
                    role:  (CI_RoleCode) publisher
                series:  (CI_Series)
                    name:  Ocean CO2
                otherCitationDetails:  [retrieved from http://cdiac.ornl.gov/ftp/oceans/CLIVAR/S04P_2011/]
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                title:  Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.), (2007): Guide to Best Practices for Ocean C O2 Measurements. PICES Special Publication 3, 191 pp.
                date:  (CI_Date)
                    date:  2007
                    dateType:  (CI_DateTypeCode) publication
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        aggregationInfo:  (MD_AggregateInformation)
            aggregateDataSetName:  (CI_Citation)
                title:  NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
                date:  (CI_Date)
                    date:  2022-04
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                    contactInfo:  (CI_Contact)
                        onlineResource:  (CI_OnlineResource)
                            linkage: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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                            name: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
                            description:  OCADS website
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                citedResponsibleParty:  (CI_ResponsibleParty)
                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
                    role:  (CI_RoleCode) author
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                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                otherCitationDetails:  [accessed 2024-02-08]
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            initiativeType:  (DS_InitiativeTypeCode) program
        language:
          LanguageCode:  eng; USA
        characterSet:  (MD_CharacterSetCode) utf8
        topicCategory:  (MD_TopicCategoryCode) environment
        topicCategory:  (MD_TopicCategoryCode) oceans
        extent:  (EX_Extent)
            geographicElement:  (EX_GeographicBoundingBox)
                westBoundLongitude:  165.692
                eastBoundLongitude:  -66.582
                southBoundLatitude:  -77.692
                northBoundLatitude:  -58.803
            temporalElement:  (EX_TemporalExtent)
                extent:
                  TimePeriod:
                    beginPosition:  2011-02-19
                    endPosition:  2011-04-23
        supplementalInformation:  These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI. In this accession, NCEI has archived multiple versions of these data. The latest (and best) version of these data has the largest version number.
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    distributionInfo:  (MD_Distribution)
        distributor:  (MD_Distributor)
            distributorContact:  (CI_ResponsibleParty)
                organisationName:
                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
                contactInfo:  (CI_Contact)
                    phone:  (CI_Telephone)
                        voice:  +1-301-713-3277
                    address:  (CI_Address)
                        electronicMailAddress:  NCEI.Info@noaa.gov
                role:  (CI_RoleCode) pointOfContact
            distributionOrderProcess:  (MD_StandardOrderProcess)
                fees:  In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
                orderingInstructions:  Contact NCEI for other distribution options and instructions.
            distributorFormat:  (MD_Format)
                name:  CSV
                version: (unknown)
            distributorTransferOptions:  (MD_DigitalTransferOptions)
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                  Real:  17.812
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                    linkage: https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0109933.html
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                    applicationProfile:  Web browser
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                    linkage: https://doi.org/10.3334/cdiac/otg.clivar_s04p_2011
                    protocol:  HTTPS
                    applicationProfile:  Web browser
                    name:  NCEI Dataset Landing Page
                    description:  Navigate directly to the URL for a descriptive web page with download links.
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                onLine:  (CI_OnlineResource)
                    linkage: https://www.ncei.noaa.gov/archive/accession/oas/109933
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                    name:  Descriptive Information
                    description:  Navigate directly to the URL for a descriptive web page with download links.
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                    linkage: https://www.ncei.noaa.gov/archive/accession/download/109933
                    protocol:  HTTPS
                    applicationProfile:  Web browser
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                    description:  Navigate directly to the URL for data access and direct download.
                    function:  (CI_OnLineFunctionCode) download
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                    linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0058/0109933/
                    protocol:  FTP
                    applicationProfile:  Any FTP client
                    name:  FTP
                    description:  These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
                    function:  (CI_OnLineFunctionCode) download
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) dataset
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            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0109933 v1.1 was published.
                dateTime:
                  DateTime:  2013-07-03T19:02:08Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0109933 v1.1
                        date:  (CI_Date)
                            date: (inapplicable)
                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0109933/1.1
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0109933 v1.1
                                    description:  published 2013-07-03T19:02:08Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0109933 was revised and v2.2 was published.
                rationale:  Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
                dateTime:
                  DateTime:  2014-01-07T16:01:11Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0109933 v2.2
                        date:  (CI_Date)
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                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0109933/2.2
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0109933 v2.2
                                    description:  published 2014-01-07T16:01:11Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0109933 was revised and v3.3 was published.
                rationale:  Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
                dateTime:
                  DateTime:  2016-02-19T17:17:10Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0109933 v3.3
                        date:  (CI_Date)
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                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0109933/3.3
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0109933 v3.3
                                    description:  published 2016-02-19T17:17:10Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
            processStep:  (LE_ProcessStep)
                description:  NCEI Accession 0109933 was revised and v4.4 was published.
                rationale:  Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
                dateTime:
                  DateTime:  2017-11-18T03:15:08Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0109933 v4.4
                        date:  (CI_Date)
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                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0109933/4.4
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0109933 v4.4
                                    description:  published 2017-11-18T03:15:08Z
                                    function:  (CI_OnLineFunctionCode) download
                            role: (inapplicable)
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) dataset
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: The replicate samples (N=314) were interspersed throughout the station analysis for quality assurance and integrity of the coulometer cell solutions. No systematic differences between the replicates were observed; Standardization description: SOMMA (Single Operator Multiparameter Metabolic Analyzer; CRM batch number: Batch 106.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: potentiometric; Cell type (open or closed): Open; Curve fitting method: Total alkalinity measurements were made using an open-cell, two-stage, potentiometric titration procedure similar to that used to certify reference materials for total alkalinity (see Dickson et al., 2003), except that samples were not weighed into the titration vessel.; Uncertainty: Precision ~ 1.5 μmol/kg, Accuracy ~ 2.0 μmol/kg; Method reference: Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.), (2007): Guide to Best Practices for Ocean C O2 Measurements. PICES Special Publication 3, 191 pp. Dickson, A. G., Afghan, J. D. & Anderson, G. C., 2003. Reference materials for oceanic CO2 analysis: A method for the certification of total alkalinity. Marine Chemistry 80, 185-197..
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: pH; Abbreviation: pH; pH scale: Total scale; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25; Detailed sampling and analyzing information: pH (mmol/kg H2O) on the total scale was measured using an Agilent 8453 spectrophotometer according to the methods outlined by Clayton and Byrne (1993). A RTE17 water bath maintained spectrophotometric cell temperature at 25.0C.; Uncertainty: The precision of the data can be accessed from measurements of duplicate samples, and certified reference material (CRM) Batch 106 (Dr. Andrew Dickson, UCSD). CRMs were measured approximately every other. The mean and standard deviation for the CRMs was 7.9168+/- 0.0031 (n=110).the accuracy of the pH measurements is underway, and large changes (~0.01) in the final reported values are likely. Confidence in the precision of the measurements remains high, and likely changes would be a simple offset or an offset that is a simple function of reported pH..
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SF6; Abbreviation: SF6; Unit: FMOL/KG; Controlled vocabulary name: Sulfur Hexaflouride (SF6); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TOT; Abbreviation: PH_TOT; Unit: @20C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: DOC; Abbreviation: DOC; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED ORGANIC CARBON; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TDN; Abbreviation: TDN; Unit: UMOL/KG; Controlled vocabulary name: Total Dissolved Nitrogen (TDN); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TRITUM; Abbreviation: TRITUM; Unit: TU; Controlled vocabulary name: Tritium (Hydrogen isotope); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TRITER; Abbreviation: TRITER; Unit: TU; In-situ / Manipulation / Response variable: in-situ .
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    dataQualityInfo:  (DQ_DataQuality)
        scope:  (DQ_Scope)
            level:  (MD_ScopeCode) repository
            levelDescription:  (MD_ScopeDescription)
                other:  NOAA National Centers for Environmental Information
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
                dateTime:
                  DateTime:  2015-04-22T00:00:00
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        maintenanceNote:  NCEI Accession 0109933 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  spectrophotometer
            type:  spectrophotometer
            description:  spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
        platform:  (MI_Platform)
            identifier:  (MD_Identifier)
                code:  RV Nathaniel B. Palmer
            description:  Updated information from ICES for the vessel NATHANIEL B. PALMER from UNITED STATES. Use 3206 for all data attributed to the vessel NATHANIEL B. PALMER from UNITED STATES. This platform has a current Call Sign = WPB3210 and two previous call signs, related to owner/company name changes since 1992. Previous call signs for NATHANIEL B. PALMER are: KUS1475 (1992 - ca. 1996) WCE9345 (ca. 1996 - mid-2006) WBP3210 (mid-2006 to present) Name : NATHANIEL B. PALMER Flag : UNITED STATES - US (ISO Country Code) Call Sign : WBP3210 Title : RV Platform Class : 31 Research vessel IMO : 9007257 Commissioned Date : 1992 Current Length : 86 Built : 1992-03 Notes : Data also found under previous call sign KUS1475 Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=241527 Confirmed by NOAA on 2013-11-19.
            instrument: (missing)