Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon (DIC), pH on seawater scale, total alkalinity (TA), water temperature, salinity and other variables collected from discrete sample and profile observations during NOAA Ship Ronald H. Brown cruise 31RBOACES24N_2, OACES-98 (EXPOCODE 33RO19980123), along the WOCE Section A05 in the North Atlantic Ocean from 1998-01-23 to 1998-02-23 (NCEI Accession 0113920)
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title: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon (DIC), pH on seawater scale, total alkalinity (TA), water temperature, salinity and other variables collected from discrete sample and profile observations during NOAA Ship Ronald H. Brown cruise 31RBOACES24N_2, OACES-98 (EXPOCODE 33RO19980123), along the WOCE Section A05 in the North Atlantic Ocean from 1998-01-23 to 1998-02-23 (NCEI Accession 0113920)
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abstract: This dataset includes chemical, discrete sample, physical and profile data collected during NOAA Ship Ronald H. Brown cruise 31RBOACES24N_2, OACES-98 (EXPOCODE 33RO19980123), along the WOCE Section A05 in the North Atlantic Ocean from 1998-01-23 to 1998-02-23. These data include partial pressure (or fugacity) of carbon dioxide (pCO2), dissolved inorganic carbon (DIC), pH on seawater scale, total alkalinity (TA), water temperature, salinity, silicate, nitrate, nitrite, phosphate, chlorofluorocarbons (CFC-11, CFC-12, CFC-113), carbon tetrachloride (CCL4), delta carbon-13, delta carbon-14, dissolved oxygen and total organic carbon (TOC). The instruments used to collect these data include Alkalinity titration, CTD, Coulometer for DIC measurement, flask with closed headspace for discrete carbon dioxide (CO2) measurement, bottle and spectrophotometer. These data were collected by Kitack Lee of Pohang University of Science and Technology; School of Environmental Science and Engineering, Frank J. Millero of Rosenstiel School of Marine and Atmospheric Science and Rik Wanninkhof and D. Bitterman of NOAA Atlantic Oceanographic and Meteorological Laboratory as part of the WOCE_AR01(A05), CARINA/33RO19980123 data set. The CARINA (CARbon dioxide IN the Atlantic Ocean) data synthesis project is an international collaborative effort of the EU IP CARBOOCEAN, and U.S. partners. It has produced a merged internally consistent dataset of open ocean subsurface measurements for biogeochemical investigations, in particular, studies involving the carbon system. The original focus area was the North Atlantic Ocean, but over time the geographic extent expanded and CARINA now includes data from the entire Atlantic, the Arctic Ocean, and the Southern Ocean.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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processStep: (LE_ProcessStep)
description: NCEI Accession 0113920 was revised and v3.3 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2020-10-08T00:27:25Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0113920 v3.3
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0113920/3.3
protocol: HTTPS
name: NCEI Accession 0113920 v3.3
description: published 2020-10-08T00:27:25Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: 1000 replicate samples was run using a new coulometer cell solution. No systematic difference between the replicates was observed. the 1000 m replicate samples run on both PMEL1 and PMEL2 combined had a standard deviation of 1.3 μmol/kg for 32 sets of duplicates, and the results of the surface replicates yielded a standard deviation of 0.9 μmol/kg for 98 sets of duplicates.; CRM batch number: 40=1985.8 μmol/kg.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Metrohm 665 Dosimat; Cell type (open or closed): Closed; Curve fitting method: The titration system used to determine TA consisted of a Metrohm 665 Dosimat titrator and an Orion 720A pH meter controlled by a personal computer (Millero et al., 1993); Uncertainty: The volume of HCl delivered to the cell is traditionally assumed to have a small uncertainty (Dickson, 1981) and is equated with the digital output of the titrator. Calibrations of the Dosimat burettes with Milli Q water at 25C indicated that the systems deliver 3.000 ml (the value for a titration of seawater) to a precision of 0.0004 ml. This uncertainty resulted in an error of 0.4 μmol/kg in TA.; Method reference: Bradshaw, A. L. and Brewer, P. G., 1988. High precision measurements of alkalinity and total carbon dioxide in seawater by potentiometric titration- 1. Presence of unknown protolyte(s)?, Mar. Chem., 23, 69-86. Millero, F. J., Zhang, J. Z., Lee, K., and Campbell, D. M., 1993. Titration alkalinity of seawater, Mar. Chem., 44, 153-16. Taylor, J.K., and Smith S.W., 1959. Precise coulometric titration of acids and bases. J. Res. Natl. Bur. Stds., 69A, 153-159. Marinenko, G., and Taylor, J.K., 1968. Electrochemical equivalents of benzoic and oxalic acid. Anal. Chem., 40, 1645-1651. Dickson, A.G., 1981. An exact definition of total alkalinity and a procedure for the estimation of alkalinity and total CO2 from titration data. Deep-Sea Res., 28, 609-623. Millero, F. J., Zhu, X., Liu, X., Roche, M. P., Moore, C., Jolliff, J., 2000. The pH and TA along 24 °North in the Atlantic Ocean. University of Miami Technical Report No. RSMAS-2000-03, 41 pp. Mehrbach, C., Culberson, C.H., Hawley, J.E., and Pytkowicz, R.M., 1973. Measurements of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure, Limnol. Oceanogr., 18, 897-907. Dickson, A.G. and Millero, F.J., 1987. A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media, Deep-Sea Res., 34, 1733-1743.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH; pH scale: hydrogen ion concentration ([H+]T), seawater scale ([H+]sw); Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25C; Detailed sampling and analyzing information: Seawater pH was measured using the spectrophotometric procedure (Byrne, 1987) and the indicator calibration of Clayton and Byrne (1993). The indicator was an 8.0-mM solution of Kodak m-cresol purple sodium salt (C21H17O5Na) in MilliQ water. The absorbance ratio of the concentrated indicator solution (RI = 578A/434A) was 0.95. All absorbance ratio measurements were obtained in the thermostatted (25.0+/-0.05C) cell compartments of HP 8453 UV-visible Diode Array Spectrophotometers. Measurements of pH were taken at 25C on the total hydrogen ion concentration ([H+]T) scale, in mol/kg solution, and converted to seawater scale ([H+]sw). The overall precision of the pH measurements obtained from the duplicate samples was +/-0.0006. A total of 1997 samples were measured and 24 of them were rejected.; Uncertainty: The overall precision of the pH measurements obtained from the duplicate samples was +/-0.0006. A total of 1997 samples were measured and 24 of them were rejected..
processStep: (LE_ProcessStep)
description: Parameter or Variable: pCO2 (fCO2) discrete; Abbreviation: fCO2; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Seawater volume: 120 mL; Headspace volume: 5 mL; Temperature of measurement: 20C; Detailed sampling and analyzing information: GAS CHROMATOGRAPHIC (GC) METHOD (Neill et al. 1997); Sample replicate information: The precision of the fCO2 measurements was estimated at 0.86% of the signal based on 89 replicate samples.; Uncertainty: 0.86%; Method reference: Neill, C., Johnson, K.M., Lewis, E., and Wallace, D.W.R., 1997. Accurate headspace analysis of fCO2 in discrete water samples using batch equilibration. Limnol. Oceanogr., 42(8), 1774-1783.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC113; Abbreviation: CFC113; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-113 (CFC-113); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CCL4; Abbreviation: CCL4; Unit: PMOL/KG; Controlled vocabulary name: Carbon tetrachloride (CCL4); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: FCO2; Abbreviation: FCO2; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: FCO2_TMP; Abbreviation: FCO2_TMP; Unit: DEG_C; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH; Abbreviation: PH; Unit: SWS@25C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TOC; Abbreviation: TOC; Unit: UMOL/L; Controlled vocabulary name: Total Organic Carbon (TOC); In-situ / Manipulation / Response variable: in-situ .
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) repository
levelDescription: (MD_ScopeDescription)
other: NOAA National Centers for Environmental Information
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
dateTime:
DateTime: 2015-04-22T00:00:00
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0113920 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: coulometer for DIC measurement
type: coulometer for DIC measurement
description: measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: flask with closed headspace for discrete CO2 measurement
type: flask with closed headspace for discrete CO2 measurement
description: discrete carbon dioxide (CO2) measurement
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: spectrophotometer
type: spectrophotometer
description: spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: titrator
type: titrator
description: titrator
platform: (MI_Platform)
identifier: (MD_Identifier)
code: NOAA Ship Ronald H. Brown
description: Updated information from ICES for UNITED STATES platform Ronald H. Brown Flag : UNITED STATES - US (ISO Country Code) Call Sign : WTEC Title : NOAA Ship Platform Class : Research vessel IMO : 9105786 Pennant : R 104 Commissioned Date : 1997-07-19 Current Length : 83.5 Built : 1997 Information Source : http://www.moc.noaa.gov/rb/index.html (URL) Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=277516 *General Comments:* Name RESEARCHER II planned during build was never used.
instrument: (missing)
