Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using CTD, Carbon dioxide (CO2) gas analyzer and other instruments from THOMAS G. THOMPSON in the Bismarck Sea, Coral Sea and others from 1993-10-05 to 1993-11-10 (NCEI Accession 0115019)
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title: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using CTD, Carbon dioxide (CO2) gas analyzer and other instruments from THOMAS G. THOMPSON in the Bismarck Sea, Coral Sea and others from 1993-10-05 to 1993-11-10 (NCEI Accession 0115019)
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abstract: This dataset includes Surface underway, chemical, discrete sample, meteorological, physical and profile data collected from THOMAS G. THOMPSON in the Bismarck Sea, Coral Sea, Gulf of Guinea, North Atlantic Ocean, North Pacific Ocean, Solomon Sea, South Atlantic Ocean and South Pacific Ocean from 1993-10-05 to 1993-11-10. These data include BAROMETRIC PRESSURE, CHLOROFLUOROCARBON-11 (CFC-11), CHLOROFLUOROCARBON-12 (CFC-12), DELTA CARBON-13, DELTA CARBON-14, DELTA HELIUM-3, DISSOLVED INORGANIC CARBON (DIC), DISSOLVED OXYGEN, HELIUM, HYDROSTATIC PRESSURE, NEON, NITRATE, NITRITE, Partial pressure (or fugacity) of carbon dioxide - atmosphere, Partial pressure (or fugacity) of carbon dioxide - water, Potential temperature (theta), SALINITY, SEA SURFACE TEMPERATURE, TOTAL ALKALINITY (TA), Tritium (Hydrogen isotope), WATER TEMPERATURE, phosphate and silicate. The instruments used to collect these data include CTD, Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and bottle. These data were collected by Robert M. Key of Princeton University; Department of Geosciences; Program in Atmospheric and Ocean Sciences and Christopher Sabine of US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory as part of the WOCE P10 and WOCE_P10 data set. CDIAC associated the following cruise ID(s) with this data set: 3250TN026_1 and WOCE_P10 The World Ocean Circulation Experiment (WOCE) was a major component of the World Climate Research Program with the overall goal of better understanding the ocean's role in climate and climatic changes resulting from both natural and anthropogenic causes. The CO2 survey took advantage of the sampling opportunities provided by the WOCE Hydrographic Program (WHP) cruises during this period between 1990 and 1998. The final collection covers approximately 23,000 stations from 94 WOCE cruises.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
credit: Funding Information: NSF
credit: Funding Information: NOAA
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keyword: TCARBN
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Anchor: https://gcmd.earthdata.nasa.gov/kms/concept/d8efbcb9-9ab3-4016-b7ff-6426cd0bf545 EQUILIBRATORS
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Anchor: https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/3250 THOMAS G. THOMPSON (call sign: KTDQ, ICES code: 3250, 1991)
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Anchor: https://gcmd.earthdata.nasa.gov/kms/concept/a4202721-0cba-4fa1-853f-890f146b04f9 OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN
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Anchor: https://gcmd.earthdata.nasa.gov/kms/concept/fa0ec8a7-ebed-4f2d-834b-1fa6a1c2e0ed OCEAN > PACIFIC OCEAN > SOUTH PACIFIC OCEAN
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otherConstraints: Cite as: Sabine, Christopher L.; Key, Robert M.; Hall, Melinda M.; Kozyr, Alex (ed.) (2013). Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using CTD, Carbon dioxide (CO2) gas analyzer and other instruments from THOMAS G. THOMPSON in the Bismarck Sea, Coral Sea and others from 1993-10-05 to 1993-11-10 (NCEI Accession 0115019). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.ndp071. Accessed [date].
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title: Sabine, C. L., R. M. Key, M. Hall, and A. Kozyr (ed.) (1999). Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas G. Thompson Cruise in the Pacific Ocean (WOCE Section P10, October 5 - November 10, 1993). ORNL/CDIAC-122, NDP-071. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee, WOCE P10, WOCE_P10.
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title: NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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LanguageCode: eng; USA
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beginPosition: 1993-10-05
endPosition: 1993-11-10
supplementalInformation: These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI. In this accession, NCEI has archived multiple versions of these data. The latest (and best) version of these data has the largest version number.
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fees: In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
orderingInstructions: Contact NCEI for other distribution options and instructions.
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linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0062/0115019/
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function: (CI_OnLineFunctionCode) download
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dataQualityInfo: (DQ_DataQuality)
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description: NCEI Accession 0115019 v1.1 was published.
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DateTime: 2013-12-12T22:10:08Z
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description: NCEI Accession 0115019 was revised and v2.2 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
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DateTime: 2017-02-22T19:48:15Z
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dataQualityInfo: (DQ_DataQuality)
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description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Detailed sampling and analyzing information: Samples were analyzed using a computer controlled single-operator multiparameter metabolic analyzer (SOMMA) system and UIC model 5011 coulometer following standard methods (Johnson et al. 1985, 1987; DOE 1994); CRM batch number: 25 26 27.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Single point titration; Cell type (open or closed): Closed; Curve fitting method: Samples analyzed at sea were brought to 25C in a water bath, then pumped into a water- jacketed, 100-cm3, closed titration cell with a peristaltic pump. The cell design is described in the DOE Handbook (DOE 1994). The acid titrant was made by adding concentrated HCl to a 0.5 molar NaCl solution to give a normality of approximately 0.2. The calibrated acid normality (0.195091 +/- 0.000041 μmol/kg solution) was determined immediately after the cruise by A. Dickson of SIO using the coulometric technique described by Millero et al. (1993). The titration system consisted of a personal computer, a Metrohm 665 Dosimat digital burette, an Orion 720A pH meter, and a Corning semi micro pH electrode. Using a program similar to those used by previous investigators (Bradshaw and Brewer 1988; Millero et al. 1993), the system automatically titrated the sample past the carbonic acid endpoint with electromotive force (emf) intervals of approximately 13 mV. Alkalinity samples returned to the laboratory for analysis were titrated using the same methods described for the at-sea samples. However, since accurate analytical balances were available, the cell volume was determined by careful weighing of the titration cell both empty and full of deionized water at a known temperature.; Uncertainty: The overal precision of TALK measurements was +/-4 μmol/kg The mean value for CRMs titrated over this period (~35 days) was 2207.6 +/- 3.5 μmol/kg (N = 40). The mean difference between duplicate P10 samples run in the lab was 3.8 +/- 5.2 μmol/kg (N = 12), not quite as good as the samples run at sea but not significantly different from zero. The mean difference between the samples run in the laboratory and the replicates run at sea immediately after collection was 3.8 +/- 4.0 μmol/kg indicating that the storage of the samples did not affect the TALK values.; Method reference: Bradshaw A. L., and P. G. Brewer. 1988. High-precision measurements of alkalinity and total carbon dioxide in seawater by potentiometric titration-1. Presence of unknown protolyte (s)? Marine Chemistry 23:69-86. DOE (U.S. Department of Energy). 1994. Handbook of Methods for the Analysis of the Various Parameters of the Carbon Dioxide System in Sea Water. Ver. 2. ORNL/CDIAC-74. A. G. Dickson and C. Goyet (eds.). Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tenn. Millero, F. J., J.-Z. Zhang, K. Lee, and D. M. Campbell. 1993. Titration alkalinity of seawater. Marine Chemistry 44:153-65..
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDPRS; Abbreviation: CTDPRS; Unit: DBAR; Controlled vocabulary name: HYDROSTATIC PRESSURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TRITUM; Abbreviation: TRITUM; Unit: TU; Controlled vocabulary name: Tritium (Hydrogen isotope); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: HELIUM; Abbreviation: HELIUM; Unit: NMOL/KG; Controlled vocabulary name: HELIUM; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DELHE3; Abbreviation: DELHE3; Unit: PERCNT; Controlled vocabulary name: DELTA HELIUM-3; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DELC14; Abbreviation: DELC14; Unit: /MILLE; Controlled vocabulary name: DELTA CARBON-14; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DELC13; Abbreviation: DELC13; Unit: /MILLE; Controlled vocabulary name: DELTA CARBON-13; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: C14ERR; Abbreviation: C14ERR; Unit: /MILLE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NEON; Abbreviation: NEON; Unit: NMOL/KG; Controlled vocabulary name: NEON; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: XCO2_AIR; Abbreviation: XCO2_AIR; Unit: PPM; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: XCO2_WAT; Abbreviation: XCO2_WAT; Unit: PPM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SST; Abbreviation: SST; Unit: DEG_C; Controlled vocabulary name: SEA SURFACE TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SSS; Abbreviation: SSS; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ATM_PRE; Abbreviation: ATM_PRE; Unit: ATM; Controlled vocabulary name: BAROMETRIC PRESSURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: EQ_TMP; Abbreviation: EQ_TMP; Unit: DEG_C; In-situ / Manipulation / Response variable: in-situ .
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) repository
levelDescription: (MD_ScopeDescription)
other: NOAA National Centers for Environmental Information
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
dateTime:
DateTime: 2015-04-22T00:00:00
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0115019 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: carbon dioxide (CO2) gas analyzer
type: carbon dioxide (CO2) gas analyzer
description: measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: showerhead equilibrator
type: showerhead equilibrator
description: extracts dissolved CO2 from water A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside. Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
platform: (MI_Platform)
identifier: (MD_Identifier)
code: R/V THOMAS G. THOMPSON
description: Use this platform for data attributed to R/V Thomas G. Thompson that were collected between July 1991 and present. R/V Thomas G. Thompson (AGOR-23) Owned by US Navy, leased to University of Washington. Active dates: July 1991 (Source: http://www.navsource.org/archives/09/57/5723.htm, last accessed on 20 Dec 2011)
instrument: (missing)
