National Coral Reef Monitoring Program: Dissolved inorganic carbon, total alkalinity, pH and other variables collected from surface discrete observations using infrared dissolved inorganic carbon analyzer, alkalinity titrator and other instruments from Caribbean Sea, Salt River Bay, St. Croix, St. Thomas Brewers Bay, U.S. Virgin Islands (Class II climate monitoring sites) from 2013-09-09 to 2014-07-02 (NCEI Accession 0132021)
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title: National Coral Reef Monitoring Program: Dissolved inorganic carbon, total alkalinity, pH and other variables collected from surface discrete observations using infrared dissolved inorganic carbon analyzer, alkalinity titrator and other instruments from Caribbean Sea, Salt River Bay, St. Croix, St. Thomas Brewers Bay, U.S. Virgin Islands (Class II climate monitoring sites) from 2013-09-09 to 2014-07-02 (NCEI Accession 0132021)
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abstract: This dataset contains data collected to monitor coral reef carbonate chemistry over time, at US affiliated coral reef sites, through quantifying key chemical parameters that are expected to be impacted by ocean acidification. This effort addresses OAP programmatic themes 1 and 5 by maintaining the coral reef portion of the OA monitoring network and developing a procedure for data synthesis, assimilation, and distribution. Incorporating an interdisciplinary approach, this project will collect, process, analyze, and steward dissolved inorganic carbon (DIC) and total alkalinity (TA) water sample data to document seawater carbonate chemistry at Class 0, II, III climate monitoring sites in coral reef areas of the US Atlantic and Pacific regions.
purpose: Provide high-quality carbonate chemistry data (dissolved inorganic carbon and total alkalinity) for US coral reef areas at several spatial and temporal scales, in close partnership with the larger CRCP NCRMP and OAP/PMEL NOA-ON efforts.
credit: Funding Information: NOAA Ocean Acidification Program (Coral Reef Ocean Acidification Monitoring: Atlantic Test Bed, OAPFY13.03.CRCP.002)
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title: Manzello, Derek P.; Enochs, Ian C.; Kolodziej, Graham; Carlton, Renée D.; Valentino, Lauren M. (2015). Dissolved inorganic carbon, total alkalinity, pH and other variables collected from surface discrete observations using Alkalinity titrator, infrared dissolved inorganic carbon analyzer and other instruments from the coastal waters of Puerto Rico, U.S. Virgin Islands, Dry Tortugas, and Flower Garden Banks (Class 0 climate monitoring sites) from 2013-07-08 to 2014-09-08 (NCEI Accession 0132020). NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.7289/v5d50k2g.
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title: Manzello, Derek P.; Enochs, Ian C.; Kolodziej, Graham; Carlton, Renée D.; Valentino, Lauren M. (2015). National Coral Reef Monitoring Program: Dissolved inorganic carbon, total alkalinity, pH and other variables collected from surface discrete observations using infrared dissolved inorganic carbon analyzer, alkalinity titrator and other instruments from the North Atlantic Ocean near Key West, Florida (Class III climate monitoring sites) from 2012-03-23 to 2014-12-11 (NCEI Accession 0132022). NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.7289/v54m92mv.
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beginPosition: 2013-09-09
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supplementalInformation: PRINCIPAL INVESTIGATORS: Manzello, Derek P; Enochs, Ian C; Kolodziej, Graham E.; Carlton, Renee D.; Valentino, Lauren M. FUNDING AGENCY: NOAA's Ocean Acidification Program (OAP). PROJECT TITLE: Coral Reef Ocean Acidification Monitoring: Atlantic Test Bed. PROJECT ID: OAPFY13.03.CRCP.002.
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fees: In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
orderingInstructions: Contact NCEI for other distribution options and instructions.
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function: (CI_OnLineFunctionCode) download
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dataQualityInfo: (DQ_DataQuality)
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description: published 2015-10-15T14:23:11Z
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
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description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Unit: umol/kg; Observation type: discrete water sample; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: Measured; Sampling instrument: Borosilicate bottle; Analyzing instrument: Apollo Sci-tech DIC Analyzer, model no. AS-C3; Detailed sampling and analyzing information: Measurements drawn according to procedures in the Guide to best practices for ocean CO2 measurements (Dickson et al., 2007). Borosilicate bottle were rinsed and filled from bottom, leaving a minimal amount of headspace while making sure no bubbles were introduced. Then 0.2 ml of saturated HgCl2 solution was added, bottles were sealed with glass stoppers lightly covered with Apiezon-L grease, and were stored at room temperature to be sent back to the lab for analysis on the Apollo Sci-tech DIC Analyzer.; Replicate information: duplicate samples analyzed; Standardization description: Duplicate samples are run in addition to Certified Reference Material (CRM), supplied by Dr. A. Dickson of UCSD; Standardization frequency: Along with duplicate samples being run throughout, CRMs are run at the beginning and end of each sampling period; CRM manufacturer: Andrew Dickson's lab at Scripps Institute of Oceanography; CRM batch number: CRM 114, 123, 104, 130, 138; Preservation method: saturated Mercury Chloride (HgCl2); Preservative volume: 200um; Method reference: Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Unit: uequiv/kg; Observation type: discrete water sample; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: Measured; Sampling instrument: Borosilicate bottle; Analyzing instrument: Apollo Sci-tech Alkalinity Titrator, model no. AS-ALK2; Type of titration: Gran titration; Cell type (open or closed): Open; Detailed sampling and analyzing information: Samples run using remaining water from the same sample bottles used for DIC. Refer to DIC for more information on sampling and conservation of samples. Water samples were titrated with HCl solution provided by Dr. Andrew Dickson of UCSD (0.25175 moles per kilogram-solution).; Replicate information: 500-ml sets of duplicate samples; Standardization description: Duplicate samples are run in addition to Certified Reference Material (CRM), supplied by Dr. A. Dickson of UCSD; Standardization frequency: Along with duplicate samples being run throughout, CRMs are run at the beginning and end of each sampling period; CRM manufacturer: Andrew Dickson's lab at Scripps Institute of Oceanography; CRM batch number: CRM 114, 123, 104, 130, 138; Preservation method: saturated Mercury Chloride (HgCl2); Preservative volume: 200um; Preservative correction: no correction.; Method reference: Used spectrometric method from Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH; pH scale: NBS; Observation type: discrete water sample; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: Measured; Sampling instrument: Borosilicate bottle; Analyzing instrument: Apollo Sci-tech Alkalinity Titrator, model no. AS-ALK2; Detailed sampling and analyzing information: Same sample bottle for pH, DIC and TA analyses. Refer to DIC for more information on sampling and conservation of samples.; Replicate information: 500-ml sets of duplicate samples; Standardization description: YSI pH buffers; Standardization frequency: daily; pH standard values: 4.0, 7.0, 10.0 +/-0.01 @ 25 deg C; At what temperature was pH reported: temperature during analysis; Method reference: Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pCO2 (fCO2) discrete; Abbreviation: pCO2; Unit: uatm; Observation type: discrete water sample; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: calculated; Calculation method and parameters: CO2SYS_macro_MAC_PC_2011.xls; Storage method: Borosilicate bottle; Method reference: Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Temperature measured during sample collection in degrees Celsius; Abbreviation: Temp at collection (deg C); Unit: oC; Observation type: surface measurement; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: measured; Sampling instrument: Borosilicate bottle; Analyzing instrument: YSI EcoSense EC300A portable conductivity, salinity, and temperature instrument; Duration: one-time measurement; Detailed sampling and analyzing information: Model EC300A; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Salinity measured during sample collection in psu; Abbreviation: Salinity (psu); Unit: psu; Observation type: surface measurement; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: measured; Sampling instrument: Borosilicate bottle; Analyzing instrument: YSI EcoSense EC300A portable conductivity, salinity, and temperature instrument; Duration: one-time measurement; Detailed sampling and analyzing information: Model EC300A; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Depth in meters; Abbreviation: Depth (m); In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: measured; Sampling instrument: depth gauge; Duration: one-time measurement; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Aragonite saturation state; Abbreviation: Omega Aragonite; In-situ / Manipulation / Response variable: in-situ observation; Measured or calculated: calculated; Calculation method and parameters: CO2SYS_macro_MAC_PC_2011.xls; Sampling instrument: Borosilicate bottle; Duration: one-time measurement; Researcher name: Derek Manzello; Researcher institution: Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration .
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maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: multi-parameter water quality sensor
type: multi-parameter water quality sensor
description: used to measure temperature, salinity, dissolved oxygen, and other parameters Instrument used to measure temperature, salinity, dissolved oxygen, and other parameters, often used to measure water quality parameters. Can be a hand-held instrument or a sonde for unattended monitoring. Often used in coastal water monitoring stations. YSI is the preeminent brand (as of 2024).
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer
type: Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer
description: A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined with a non-dispersive infrared (NDIR) carbon dioxide analyzer.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: pH sensor
type: pH sensor
description: generic meter used to measure pH Any of a class of instruments used to quantify pH in a water or other type of sample.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: titrator
type: titrator
description: titrator
