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Partial pressure of carbon dioxide (pCO2), temperature, salinity and other variables collected from surface underway observations using shower head equilibrator, carbon dioxide gas detector, and other instruments from container ship Cap Vilano in the Pacific Ocean from 2013-02-01 to 2013-06-06 (NCEI Accession 0132054)


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            title:  Partial pressure of carbon dioxide (pCO2), temperature, salinity and other variables collected from surface underway observations using shower head equilibrator, carbon dioxide gas detector, and other instruments from container ship Cap Vilano in the Pacific Ocean from 2013-02-01 to 2013-06-06 (NCEI Accession 0132054)
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                date:  2015-11-02
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                  Anchor:  DOI 10.7289/v5gx48n3
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/4697 Catherine E. Cosca
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/970 Richard A. Feely
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/976 US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory (PMEL)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/976 US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory (PMEL)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/4698 Simone R. Alin
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        abstract:  This dataset contains underway measurements of pCO2, salinity, sea surface temperature, and other parameters were collected during 3 trans-Pacific crossings in 2013 on the container ship Cap Vilano. Cruise names and expocodes: CV2013_02 (AGB620130201), CV2013_03 (AGB620130328), CV2013_05 (AGB620130524). All cruises started in Long Beach California and ended in New Zealand. This effort was conducted in support of NOAA's Climate Program Office (CPO), and Ocean Acidification Program (OAP).
        purpose:  The major objectives of the project were to and to continue a time series documenting the distribution of surface and atmospheric fCO2, salinity, temperature, and other parameters, and to characterize and map the key indicators of ocean acidification (OA) across the Pacific Ocean.
        credit:  Funding Information: NOAA Ocean Acidification Program (West Coast Ocean Acidification Monitoring Network: Volunteer Observing Ships, OAPFY12.03.PMEL.002)
        credit:  Funding Information: NOAA's Climate Program Office
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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                    date:  2015-09-30
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/71 Partial pressure (or fugacity) of carbon dioxide - atmosphere
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/70 partial pressure of carbon dioxide - water
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/307 SALINITY
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/319 SEA SURFACE TEMPERATURE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/183 carbon dioxide (CO2) gas analyzer
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/184 showerhead equilibrator
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        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: pCO2 (fCO2) autonomous; Abbreviation: fCO2W@SST; Unit: uatm; Observation type: Surface underway; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Sampling instrument: Seawater pump; Location of seawater intake: Bow; Analyzing instrument: General Oceanics 8050. PMEL system ID: GO7; Detailed sampling and analyzing information: The sampling and analyzing methods of the Neill/General Oceanics Underway pCO2 systems are described in detail in: Pierrot, D.; Neill, C.; Sullivan, K.; Castle, R.; Wanninkhof, R.; Lüger, H.; Johannessen, T.; Olsen, A.; Feely, R.A.; and Cosca, C.E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep-Sea Res., II, v. 56, pp. 512-522.; Equilibrator type: Shower head; Equilibrator volume: ~0.5 L; Is the equilibrator vented or not: Vented; Water flow rate: 3 L/min; Gas flow rate: ~0.8 L/m; How was temperature inside the equilibrator measured: Hart Scientific model 1521 digital thermometer, serial number A77488, with an NIST traceable model 5610 thermistor probe, serial number A690613. Accurate to plus/minus 0.01 degrees Celsius.; How was pressure inside the equilibrator measured: Setra 239 differential pressure transducer, accurate to plus/minus 0.15 hPa. The equilibrator was passively vented to a secondary equilibrator, and the Licor sample output was vented to the laboratory when CO2 measurements were made, thus equilibrator headspace pressure was assumed to be laboratory pressure. Pressure in the laboratory was measured with a GE Druck barometer, serial number 3013024, with an accuracy of plus/minus 0.01%.; Drying method for gas: From Pierrot, et al.: Sample air is dried in a condenser that is cooled to 4-5 oC by a Peltier thermoelectric device. This partially dried air flushes a chamber that is vented and remains at ambient pressure. The dried air inside the chamber is used as the counter flow in the Nafion tubing. A vacuum pump pulls the dried air from the chamber first through a fixed restrictor and then through the Nafion tubes, thus creating an absolute pressure and corresponding partial pressure gradient for water vapor across the membrane. When atmospheric air is measured, some of the partially dried air (80- 100 ml/min) is pushed through a Nafion tube, the analyzer and out a vent instead of flushing the chamber. The headspace gas, when being measured, is circulated in a closed loop through the analyzer at a rate similar to that of the atmospheric air (80-100 ml/min). It is dried first in the condenser, then in a Nafion tube prior to entering the analyzer and being returned to the equilibrator. Typically, the water mole fraction (xH2O) in the dried gas is about 2 parts per thousand (ppt), which corresponds to a dew point temperature of about -20 degrees Celsius. The liquid water condensed out of the sample air streams is removed by peristaltic pumps into the vent equilibrator at intervals determined by the user.; SEA CO2 gas detector manufacturer: Licor, Inc; SEA CO2 gas detector model: Licor 7000, IRG4-0560; SEA CO2 gas detector resolution: 0.2 uatm; SEA CO2 gas detector uncertainty: 0.3 uatm for equilibrator measurements, 0.2 uatm for atmospheric measurements; Standardization technique: The system runs a full cycle in approximately 7 hours. The cycle starts with 4 standard gases, then measures three rounds of 6 atmopherice samples followed by 50 surface water samples. Each new gas is flushed through the Licor Analyzer for 2 minutes prior to a stop-flow measurement.; Standardization frequency: Every 7 hours; Standard gas manufacturer: Standard gases are supplied by NOAA's Earth System Research Laboratory, Global Monitoring Division, in Boulder, CO, and are directly traceable to the WMO scale.; Standard gas concentration: LL83535, 246.77 ppm; LL108050, 399.22 ppm; LL108059, 496.103 ppm; LL154371, 628.59 ppm; Standard gas uncertainty: 0.01 ppm; Water vapor correction method: Details of the data reduction are described in Pierrot, et.al. (2009).; Temperature correction method: Details of the data reduction are described in Pierrot, et.al. (2009).; At what temperature was pCO2 reported: In situ sea surface temperature; Uncertainty: plus/minus 0.01 degrees Celsius; Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value; Method reference: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., & Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005; Researcher name: Catherine E. Cosca; Researcher institution: Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Sea Surface Temperature; Abbreviation: SST(TSG)_C; Unit: Degree Celcius; Observation type: Surface Underway; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Sampling instrument: Seabird 38, serial number 3848581-0383; Uncertainty: 0.0025 degrees Celsius.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Salinity; Abbreviation: SAL(TSG)_PERMIL; Unit: permil; Observation type: Surface Underway; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Sampling instrument: Seabird 45, serial number 4539646-0143; Uncertainty: 0.005 PSU .
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  carbon dioxide (CO2) gas analyzer
            type:  carbon dioxide (CO2) gas analyzer
            description:  measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  showerhead equilibrator
            type:  showerhead equilibrator
            description:  extracts dissolved CO2 from water A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside. Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  thermosalinograph
            type:  thermosalinograph
            description:  automated sea surface temperature and salinity instrument, usually attached to the hull of a ship Thermosalinograph is an automated Sea Surface Temperature and Salinity measurement system making measurement on board a ship using a water intake. [https://www.aoml.noaa.gov/phod/tsg/about.php 2021-01-29]
        platform:  (MI_Platform)
            identifier:  (MD_Identifier)
                code:  Cap Blanche
            description:  ICES request for the vessel Cap Blanche from ANTIGUA AND BARBUDA(AG). Name : Cap Blanche Country(s) : ANTIGUA AND BARBUDA(AG) (ISO Country Code) Platform Class : 32 Vessel of opportunity Call Sign : V2DV5 MMSI: 305347000 IMO : 9311775 Commissioned Date : 2006-07-20 Current Length : 222 Built : 2006-07-20 Previous Name (Notes): Fesco Baykal Notes : Container ship Information Sources: - http://www.marinetraffic.com/ais/details/ships/shipid:364284/mmsi:305347000/imo:9311775/vessel:CAP_BLANCHE - http://www.shipspotting.com/gallery/photo.php?lid=1677981 Confirmed by NOAA on 2015-09-28.
            instrument: (missing)