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Total alkalinity, pH on total scale, water temperature, salinity and other variables collected from discrete sample and profile observations during the R/V Sarmiento de Gamboa cruise CAIBOX (EXPOCODE 29AH20090725) in the North Atlantic Ocean from 2009-07-25 to 2009-08-13 (NCEI Accession 0144251)


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            title:  Total alkalinity, pH on total scale, water temperature, salinity and other variables collected from discrete sample and profile observations during the R/V Sarmiento de Gamboa cruise CAIBOX (EXPOCODE 29AH20090725) in the North Atlantic Ocean from 2009-07-25 to 2009-08-13 (NCEI Accession 0144251)
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                date:  2016-02-23
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                date:  2020-10-28
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                  Anchor:  DOI 10.3334/cdiac/otg.clivar_caibox_2009
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                  Anchor:  NCEI Dataset ID gov.noaa.nodc:0144251
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                  Anchor:  NCEI Accession ID 0144251
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2220 Alex Kozyr
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/4967 Aída F. Ríos
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1604 Institute of Marine Research Vigo (IIM)
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                individualName:  Miguel Gilcoto
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2758 Fiz F. Pérez
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                  Anchor:  https://orcid.org/0000-0002-2387-9201 Álvarez-Salgado, X. Antón
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1485 Spanish National Research Council
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        abstract:  This dataset includes discrete sample and profile data collected during the R/V Sarmiento de Gamboa cruise CAIBOX (EXPOCODE 29AH20090725) in the North Atlantic Ocean from 2009-07-25 to 2009-08-13. These data include total alkalinity, pH on total scale, water temperature, salinity, dissolved oxygen concentration, silicate, phosphate and nitrate. The instruments used to collect these data include Alkalinity titrator, CTD, Niskin bottles and spectrophotometer. These data were collected by Aida F. Ríos, Fiz Pérez and Miguel Gilcoto of Instituto de Investigaciones Marinas de Vigo as part of the CLIVAR_CAIBOX_2009 data set. The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
        purpose:  This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/116 DISSOLVED OXYGEN
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/589 HYDROSTATIC PRESSURE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/223 NITRATE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/257 pH
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/333 silicate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/5 total alkalinity
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/373 WATER TEMPERATURE
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/e02b0b50-a0f2-4c47-841b-9689fdb99121 EARTH SCIENCE > OCEANS > OCEAN TEMPERATURE > POTENTIAL TEMPERATURE
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/46206e8c-8def-406f-9e62-da4e74633a58 EARTH SCIENCE > OCEANS > OCEAN TEMPERATURE > WATER TEMPERATURE
            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/7e95b5fc-1d58-431a-af36-948b29fa870d EARTH SCIENCE > OCEANS > SALINITY/DENSITY > SALINITY
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                title:  OCADS Study Type
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            keyword:  ALKALI
            keyword:  CTDOXY
            keyword:  CTDSAL
            keyword:  CTDTMP
            keyword:  NITRAT
            keyword:  OXYGEN
            keyword:  PHSPHT
            keyword:  PH_TMP
            keyword:  PH_TOT
            keyword:  SILCAT
            keyword:  TA
            keyword:  THETA
            keyword:  pH
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/55facbdc-d4ed-4ee2-a74d-911b084c8ff8 OPTSPEC > Optical Spectrometer
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                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/1bb21d0f-bf48-42b5-8e09-cc0d58407e4a Ships
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                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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            keyword:
              Anchor:  https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/29AH SARMIENTO DE GAMBOA (call sign: EAKF, ICES code: 29AH)
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                title:  ICES/SeaDataNet Ship Codes
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            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/a4202721-0cba-4fa1-853f-890f146b04f9 OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN
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                title:  Global Change Master Directory (GCMD) Location Keywords
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                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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            keyword:  Atlantic Ocean
            type:  (MD_KeywordTypeCode) place
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                title:  Provider Geographic Names
                date: (inapplicable)
        resourceConstraints:  (MD_Constraints)
            useLimitation:  accessLevel: Public
        resourceConstraints:  (MD_LegalConstraints)
            useConstraints:  (MD_RestrictionCode) otherRestrictions
            otherConstraints:  Cite as: Gilcoto, Miguel; Fajar, Noelia M.; Pardo, Paula C.; Carracedo, Lidia I.; Vieitez, Vanesa; Álvarez-Salgado, X. Antón; de la Paz, Mercedes (2016). Total alkalinity, pH on total scale, water temperature, salinity and other variables collected from discrete sample and profile observations during the R/V Sarmiento de Gamboa cruise CAIBOX (EXPOCODE 29AH20090725) in the North Atlantic Ocean from 2009-07-25 to 2009-08-13 (NCEI Accession 0144251). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.clivar_caibox_2009. Accessed [date].
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            useLimitation:  Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.
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            otherConstraints:  Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
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                title:  Gilcoto, M., F. Pérez, A, Ríos, N. Fajar, P.C. Pardo, L. Carracedo, V. Vieitez, X.A. Alvarez-Salgado, and M. de la Paz (2015). Carbon Data Obtained During the R/V Sarmiento de Gamboa CAIBOX-2009 Cruise in the Atlantic Ocean (25 July - 13 August, 2009). Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee, CLIVAR_CAIBOX_2009.
                date:  (CI_Date)
                    date:  2015
                    dateType:  (CI_DateTypeCode) publication
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                    code:  CLIVAR_CAIBOX_2009
                citedResponsibleParty:  (CI_ResponsibleParty)
                    individualName:  Gilcoto, M., F. Pérez, A, Ríos, N. Fajar, P.C. Pardo, L. Carracedo, V. Vieitez, X.A. Alvarez-Salgado, and M. de la Paz
                    role:  (CI_RoleCode) author
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                            linkage: http://cdiac.ornl.gov
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                            name:  Carbon Dioxide Information Analysis Center website
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                    name:  Ocean CO2
                otherCitationDetails:  [retrieved from http://cdiac.ornl.gov/ftp/oceans/CLIVAR/CAIBOX_2009/]
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                title:  NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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                    date:  2022-04
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                otherCitationDetails:  [accessed 2024-02-08]
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        topicCategory:  (MD_TopicCategoryCode) oceans
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                westBoundLongitude:  -20.036
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            temporalElement:  (EX_TemporalExtent)
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                  TimePeriod:
                    beginPosition:  2009-07-25
                    endPosition:  2009-08-13
        supplementalInformation:  These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI. In this accession, NCEI has archived multiple versions of these data. The latest (and best) version of these data has the largest version number.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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                        voice:  +1-301-713-3277
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                        electronicMailAddress:  NCEI.Info@noaa.gov
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                fees:  In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
                orderingInstructions:  Contact NCEI for other distribution options and instructions.
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                    linkage: https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0144251.html
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                    linkage: https://doi.org/10.3334/cdiac/otg.clivar_caibox_2009
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                    linkage: https://www.ncei.noaa.gov/archive/accession/oas/144251
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                    linkage: https://www.ncei.noaa.gov/archive/accession/download/144251
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                    linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0086/0144251/
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                    description:  These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
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    dataQualityInfo:  (DQ_DataQuality)
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                description:  NCEI Accession 0144251 v1.1 was published.
                dateTime:
                  DateTime:  2016-02-23T12:42:23Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0144251 v1.1
                        date:  (CI_Date)
                            date: (inapplicable)
                            dateType:  (CI_DateTypeCode) publication
                        citedResponsibleParty:  (CI_ResponsibleParty)
                            individualName: (inapplicable)
                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0144251/1.1
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                                    name:  NCEI Accession 0144251 v1.1
                                    description:  published 2016-02-23T12:42:23Z
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                description:  NCEI Accession 0144251 was revised and v2.2 was published.
                rationale:  Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
                dateTime:
                  DateTime:  2020-10-28T20:58:34Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0144251 v2.2
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                            contactInfo:  (CI_Contact)
                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0144251/2.2
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0144251 v2.2
                                    description:  published 2020-10-28T20:58:34Z
                                    function:  (CI_OnLineFunctionCode) download
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    dataQualityInfo:  (DQ_DataQuality)
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            level:  (MD_ScopeCode) dataset
        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Potentiometric titration; Cell type (open or closed): open cell; Curve fitting method: Double single point (4.45;4.41) Open flask; TA blank correction: none (HCl is made with MilliQ water); Uncertainty: The STD of all the TALK determinations of 26 CRM samples was 3.7 µmolkg-1.; Method reference: Pérez, F.F. and F. Fraga. (1987). A precise and rapid analytical procedure for alkalinity determination. Mar. Chem., 21, 169-182.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: pH; Abbreviation: pH; pH scale: Total scale @25deg.C, the correction proposed by DelVals and Dickson (1998) was added (+0.0047) (DelValls, T.A and A.G. Dickson (1998). The pH of buffers based on 2-amino-2-hydroxymethyl-1,3-propanediol (‘tris’) in synthetic sea water. Deep-Sea Res. I, Vol. 45, 1541-1554); Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25 °C; Detailed sampling and analyzing information: Spectrophotometrically, this method consists on adding a dye solution to the seawater sample, so that the ratio between two absorbances at two different wavelengths is proportional to the sample pH.; Uncertainty: Uncertainty of +/- 0.0015.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TOT; Abbreviation: PH_TOT; Unit: @20C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: THETA; Abbreviation: THETA; Unit: DEG_C; Controlled vocabulary name: Potential temperature (theta); In-situ / Manipulation / Response variable: in-situ .
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        maintenanceNote:  NCEI Accession 0144251 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  spectrophotometer
            type:  spectrophotometer
            description:  spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
        platform:  (MI_Platform)
            identifier:  (MD_Identifier)
                code:  RV Sarmiento De Gamboa
            description:  Built 2006; Consejo Superior de Investigaciones Cientificas (CSIC) research vessel; active as of June 2007 Title: RV Current Length(M) 70.5 Platform Class: 31 Research vessel. Country: Spain IMO: 9335238
            instrument: (missing)