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Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship GORDON GUNTER in the North Atlantic Ocean and Stellwagen Bank National Marine Sanctuary from 2013-06-09 to 2013-11-25 (NCEI Accession 0144340)


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            title:  Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship GORDON GUNTER in the North Atlantic Ocean and Stellwagen Bank National Marine Sanctuary from 2013-06-09 to 2013-11-25 (NCEI Accession 0144340)
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                date:  2016-02-26
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                  Anchor:  DOI 10.25921/0t5x-n461
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2530 Rik Wanninkhof
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                  Anchor:  https://orcid.org/0000-0002-8858-5247 Barbero, Leticia
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        abstract:  This dataset includes discrete sample and profile data collected from NOAA Ship GORDON GUNTER in the North Atlantic Ocean and Stellwagen Bank National Marine Sanctuary from 2013-06-09 to 2013-11-25. These data include AMMONIUM (NH4), DISSOLVED INORGANIC CARBON (DIC), DISSOLVED OXYGEN, HYDROSTATIC PRESSURE, SALINITY, TOTAL ALKALINITY (TA), WATER TEMPERATURE, nitrate + nitrite content (concentration), pH, phosphate and silicate. The instruments used to collect these data include Alkalinity titrator, CTD, Coulometer for DIC measurement, bottle and spectrophotometer. These data were collected by Rik Wanninkhof of NOAA Atlantic Oceanographic and Meteorological Laboratory as part of the Gordon_Gunter_Coastal_Cruises_2013 data set. CDIAC associated the following cruise ID(s) with this data set: GU1302 and GU1305 The Global Coastal Carbon Data Project data includes the bottle (discrete) and surface (underway) carbon-related measurements from coastal research cruises, the data from time series cruises and coastal moorings. The coastal regions data are very important for the understanding of carbon cycle on the continental margins.
        purpose:  This dataset is available to the public for a wide variety of uses including scientific research and analysis.
        credit:  Funding Information: NOAA Ocean Acidification Program (OAP)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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              Anchor:  https://www.ncei.noaa.gov/archive/accession/0144340 0144340
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                    date:  2016-02-26
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/11 AMMONIUM (NH4)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/588 DISSOLVED INORGANIC CARBON (DIC)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/116 DISSOLVED OXYGEN
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/589 HYDROSTATIC PRESSURE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/224 nitrate + nitrite content (concentration)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/257 pH
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/263 phosphate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/307 SALINITY
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/333 silicate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/198 coulometer for DIC measurement
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              Anchor:  https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/33GG GORDON GUNTER (call sign: WTEO, ICES code: 33GG, 1998)
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/a4202721-0cba-4fa1-853f-890f146b04f9 OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN
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            keyword:  Atlantic Ocean
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            otherConstraints:  Cite as: Barbero, Leticia; Wanninkhof, Rik; Pierrot, Denis; Melrose, Donald C.; Rebuck, Nathan D.; Townsend, David W.; Thomas, Maura A.; Taylor, Christopher C. (2016). Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship GORDON GUNTER in the North Atlantic Ocean and Stellwagen Bank National Marine Sanctuary from 2013-06-09 to 2013-11-25 (NCEI Accession 0144340). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/0t5x-n461. Accessed [date].
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                otherCitationDetails:  [accessed 2024-02-08]
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        supplementalInformation:  These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI.
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                description:  NCEI Accession 0144340 v1.1 was published.
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                  DateTime:  2016-02-26T19:17:10Z
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                        title:  NCEI Accession 0144340 v1.1
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                description:  Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Detailed sampling and analyzing information: Two systems consisting of a coulometer (UIC Inc.) coupled with a Dissolved Inorganic Carbon Extractor (DICE) inlet system. DICE was developed by Esa Peltola and Denis Pierrot of NOAA/AOML and Dana Greeley of NOAA/PMEL to modernize a carbon extractor called SOMMA (Johnson et al. 1985, 1987, 1993, and 1999; Johnson 1992); Standardization description: The coulometers were calibrated by injecting aliquots of pure CO2 (99.99%) by means of an 8-port valve outfitted with two sample loops with known gas volumes bracketing the amount of CO2 extracted from the water samples for the two AOML systems.; CRM batch number: Batch 112.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Full Titration; Cell type (open or closed): Open; Curve fitting method: Semi-automatic titration systems, System 1 consists of a Metrohm 765 Dosimat titrator, a pH meter (Orion 720A, ThermoScientific), a ROSS half cell pH glass electrode (Orion 9101BN, ThermoScientific) and a reference electrode (Orion 900200, ThermoScientific). System 2 consists of a Metrohm 665 Dosimat titrator, a pH meter (Orion 2 star pH Benchtop, ThermoScientific), a ROSS half cell pH glass electrode (Orion 9101BN, ThermoScientific) and a reference electrode (Orion 900200, ThermoScientific).; Uncertainty: The precision of this method is better than 0.1% and accuracy is 0.1%.; Method reference: Millero, F. J., Zhang, J. Z., Lee, K., & Campbell, D. M. (1993). Titration alkalinity of seawater. Marine Chemistry, 44(2), 153-165..
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: pH; Abbreviation: pH; pH scale: Total Scale; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25 (±0.05) ºC; Detailed sampling and analyzing information: Agilent 8453 spectrometer setup with a custom-made temperature-controlled cell holder. "The same sample bottle was used for pH, DIC and Talk analyses, with pH being analyzed first. The samples were fixed with HgCl2 (refer to DIC for more information on sampling and storage). Samples were thermostated at 20 (+/- 0.05) degrees Celsius in a water bath. Approximately 80 ml of sample were extracted from each DIC sample bottle by syringe before DIC analysis to determine the pH. Temperature for each sample was measured before analysis using a Hart Scientific Fluke 1523 reference thermometer. Absorbance blanks were taken for each sample and 10 micro liter of purified m-cresol purple (10 mmol kg-1) were added for the analysis. The equations of Liu et al, 2011 formulated using the purified m-cresol purple indicator were used to determine pH of the samples. pH samples were analyzed at 20C. Please check accompanying readme file for additional details."; Uncertainty: Please check attached pdf for more details.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Unit: PSU; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NO2+NO3; Abbreviation: NO2+NO3; Unit: UMOL/KG; Controlled vocabulary name: nitrate + nitrite content (concentration); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: NH4; Abbreviation: NH4; Unit: UMOL/KG; Controlled vocabulary name: AMMONIUM (NH4); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TOT; Abbreviation: PH_TOT; Unit: @25C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ .
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  bottle
            type:  bottle
            description:  any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  coulometer for DIC measurement
            type:  coulometer for DIC measurement
            description:  measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  CTD
            type:  CTD
            description:  Conductivity-Temperature-Depth probe
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  spectrophotometer
            type:  spectrophotometer
            description:  spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  titrator
            type:  titrator
            description:  titrator
        platform:  (MI_Platform)
            identifier:  (MD_Identifier)
                code:  NOAA Ship Gordon Gunter
            description:  Updated information for the vessel GORDON GUNTER from UNITED STATES(US). Name : GORDON GUNTER Country(s) : UNITED STATES(US) (ISO Country Code) Platform Class : 31 Research vessel Call Sign : WTEO IMO : 8835255 Pennant : R 336 Title : NOAA Ship Commissioned Date : 1998-08-28 Current Length : 68.3 Built : 1989-05-12 Previous Name (Notes): Relentless Notes : Built as the U.S. Naval Ship RELENTLESS (T-AGOS 18). Transferred to NOAA in 1993. Information Sources: - http://www.moc.noaa.gov/gu/index.html - http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=341240 Confirmed by NOAA on 2010-09-10.
            instrument: (missing)