Dissolved inorganic carbon (DIC), total alkalinity, pH on seawater scale, partial pressure of carbon dioxide (pCO2), dissolved organic carbon (DOC), chlorofluorocarbons (CFC-11, CFC-12), temperature, salinity and other hydrographic and chemical variables collected from discrete samples and profile observations during NOAA Ship Ronald H. Brown cruise CLIVAR_A16N_2013 (EXPOCODE 33RO20130803) in the Atlantic Ocean from 2013-08-03 to 2013-10-01 (NCEI Accession 0157363)
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title: Dissolved inorganic carbon (DIC), total alkalinity, pH on seawater scale, partial pressure of carbon dioxide (pCO2), dissolved organic carbon (DOC), chlorofluorocarbons (CFC-11, CFC-12), temperature, salinity and other hydrographic and chemical variables collected from discrete samples and profile observations during NOAA Ship Ronald H. Brown cruise CLIVAR_A16N_2013 (EXPOCODE 33RO20130803) in the Atlantic Ocean from 2013-08-03 to 2013-10-01 (NCEI Accession 0157363)
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abstract: This dataset includes discrete profile measurements of dissolved inorganic carbon (DIC), total alkalinity, pH on seawater scale, partial pressure of carbon dioxide (pCO2), dissolved organic carbon (DOC), chlorofluorocarbons (CFC-11, CFC-12), temperature, salinity, dissolved oxygen, nutrients, sulfur hexafluoride (SF6), delta C13 and delta C14 obtained during NOAA Ship Ronald H. Brown cruise CLIVAR_A16N_2013 (EXPOCODE 33RO20130803) in the Atlantic Ocean from 2013-08-03 to 2013-10-01. The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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protocol: HTTPS
name: NCEI Accession 0157363 v2.2
description: published 2018-12-20T19:31:11Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: TCARBN; Unit: UMOL/KG; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Replicate information: 1-3 replicates were drawn per station (usually 3) from the surface, bottom and ~ 1000 m depths. Average difference of replicates was 1.49 μmol/kg for AOML3 and 1.69 μmol/kg for AOML 4.; Standardization description: Injection of 2 pairs of sample loops of known volume of pure CO2 bracketing the expected values of TCO2 and analysis of Certified Reference Materials supplied by Dr. A Dickson of SIO. TCO2 values were corrected for the addition of mercuric chloride and for the offset from the CRM value.; CRM batch number: 114, 129.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: ALKALI; Unit: UMOL/KG; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: potentiometric; Cell type (open or closed): closed cell; Curve fitting method: Levenberg-Marquardt nonlinear least-squares; Uncertainty: Accuracy +/- 2.2 μmol/kg based on CRM measurments (batches 114 and 129) Precision +/- 1.8 μmol/kg based on duplicate measurements; Method reference: Millero, F.J., J.-Z. Zhang, K, Lee, and D.M. Campbell, 1993: Titration alkalinity of seawater. Mar. Chem., 44, 153-165..
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: PH_SWS; pH scale: seawater; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25; Detailed sampling and analyzing information: spectrophotometric using unpurified meta-cresol purple indicator; Uncertainty: accurracy: +/- 0.003 based on TRIS and CRM measurments Precision: 0.0018 based on duplicate measurements.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pCO2 (fCO2) discrete; Abbreviation: fCO2; Unit: UATM; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Storage method: The 0.5 L "DIC" sample bottles were sealed with glass stoppers lightly covered with Apiezon-L grease and were stored at room temperature for a maximum of twelve hours prior to analysis. All samples were kept in a secondary bath at 20 ˚C (+/- 0.3 ˚C) for at least 2 hours prior to analysis. For analysis they were moved to the primary bath at 20 ˚C (+/- 0.03 ˚C).; Seawater volume: 200 mL; Headspace volume: 5 mL; Temperature of measurement: 20 ˚C; Detailed sampling and analyzing information: Circulation of dried headspace sample gas through a non-dispersive infrared analyzer (Licor model 840). The system is a prototype built by Tim Newberger (NOAA/ESRL/CIRES) and supported by C. Sweeney and T. Takahashi. For further details see the cruise report at http://cchdo.ucsd.edu/cruise/33RO20130803; Sample replicate information: Replicate samples were drawn from 52 Niskin bottles.; Temperature correction method: 4.23%/˚C; Uncertainty: Accuracy estimated at 1% based on the uncertainty of the standards. Precision was 0.18% based on the analysis of 52 pairs of replicate samples.; Method reference: Chipman, D.W., J. Marra, and T. Takahashi, 1993: Primary production at 47°N and 20°W in the North Atlantic Ocean: A comparison between the 14C incubation method and mixed layer carbon budget observations. Deep-Sea Res., II, v. 40, pp. 151-169. Wanninkhof, R., and K. Thoning, 1993: Measurement of fugacity of CO2 in surface water using continuous and discrete sampling methods. Mar. Chem., v. 44, no. 2-4, pp. 189-205. Pierrot, D., C. Neill, K. Sullivan, R. Castle, R. Wanninkhof, H. Lüger, T. Johannessen, A. Olsen, R.A. Feely, C.E. Cosca, 2009: Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep-Sea Res., II, v. 56, pp. 512-522..
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SF6; Abbreviation: SF6; Unit: FMOL/KG; Controlled vocabulary name: Sulfur Hexaflouride (SF6); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DELC14; Abbreviation: Delta C14; Unit: o/oo; Controlled vocabulary name: Delta C14; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DELC13; Abbreviation: Delta C13; Unit: o/o; Controlled vocabulary name: Delta C13; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PCO2_TMP; Abbreviation: PCO2_TMP; Unit: DEG_C; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DOC; Abbreviation: DOC; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED ORGANIC CARBON; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TDN; Abbreviation: TDN; Unit: UMOL/KG; Controlled vocabulary name: Total Dissolved Nitrogen (TDN); In-situ / Manipulation / Response variable: in-situ .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0157363 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
platform: (MI_Platform)
identifier: (MD_Identifier)
code: NOAA Ship Ronald H. Brown
description: Updated information from ICES for UNITED STATES platform Ronald H. Brown Flag : UNITED STATES - US (ISO Country Code) Call Sign : WTEC Title : NOAA Ship Platform Class : Research vessel IMO : 9105786 Pennant : R 104 Commissioned Date : 1997-07-19 Current Length : 83.5 Built : 1997 Information Source : http://www.moc.noaa.gov/rb/index.html (URL) Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=277516 *General Comments:* Name RESEARCHER II planned during build was never used.
instrument: (missing)
