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Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from unknown platforms in the South Pacific Ocean and Southern Oceans from 2010-12-28 to 2014-02-21 (NCEI Accession 0160574)


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            title:  Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from unknown platforms in the South Pacific Ocean and Southern Oceans from 2010-12-28 to 2014-02-21 (NCEI Accession 0160574)
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                date:  2017-02-22
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                  Anchor:  DOI 10.3334/cdiac/otg.tsm_ryder_bay_67s_68w
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                  Anchor:  NCEI Accession ID 0160574
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/2220 Alex Kozyr
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/5019 Dorothee C. E. Bakker
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/622 University of East Anglia; School of Environmental Sciences
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/4901 Oliver J. Legge
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1687 University of East Anglia (UEA)
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                individualName:  Hugh J. Venables
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/642 British Antarctic Survey (BAS)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/5019 Bakker, Dorothee C. E.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/622 University of East Anglia; School of Environmental Sciences
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/4901 Legge, Oliver J.
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                individualName:  Venables, Hugh J.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/642 British Antarctic Survey (BAS)
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/622 University of East Anglia; School of Environmental Sciences
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/642 British Antarctic Survey (BAS)
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        abstract:  This dataset includes chemical, discrete sample, physical and profile data collected from unknown platforms in the South Pacific Ocean and Southern Oceans (> 60 degrees South) from 2010-12-28 to 2014-02-21. These data include DISSOLVED INORGANIC CARBON (DIC), NITRATE, SALINITY, TOTAL ALKALINITY (TA), WATER TEMPERATURE, phosphate and silicate. The instruments used to collect these data include Alkalinity titrator, CTD, Coulometer for DIC measurement and bottle. These data were collected by Hugh Venables of British Antarctic Survey and Dorothee Bakker and Oliver Legge of University of East Anglia; School of Environmental Sciences as part of the TSM_Ryder_Bay_67S_68W_2010_2014 data set. CDIAC associated the following cruise ID(s) with this data set: TSM_Ryder_Bay_67S_68W_2010_2014
        purpose:  This dataset is available to the public for a wide variety of uses including scientific research and analysis.
        credit:  Funding Information: Sampling and analysis were supported by British Antarctic Survey (BAS) Polar Oceans funding from NERC and the UK Ocean Acidification Research Programme (NE/H017046/1) grant at the University of East Anglia (UEA), funded by NERC, the Department for Energy and Climate Change and the Department for Environment, Food and Rural Affairs. Analysis was also supported by the Natural Environment Research Council (NERC)(NE/L50158X)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/588 DISSOLVED INORGANIC CARBON (DIC)
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/223 NITRATE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/263 phosphate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/307 SALINITY
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/333 silicate
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/5 total alkalinity
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/373 WATER TEMPERATURE
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              Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/3 bottle
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            keyword:  Time series
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                title:  OCADS Study Type
                date: (inapplicable)
        descriptiveKeywords:  (MD_Keywords)
            keyword:  DIC
            keyword:  Nitrate
            keyword:  Phosphate
            keyword:  Salinity
            keyword:  Silicate
            keyword:  TA
            keyword:  Temperature
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                title:  Provider Variable Abbreviations
                date: (inapplicable)
        descriptiveKeywords:  (MD_Keywords)
            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/0b6020a0-2e04-407d-83af-34eabfefb870 COULOMETERS
            keyword:
              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/01cc0beb-7c9a-40ed-ad86-0661b41aee53 CTD > Conductivity, Temperature, Depth
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                title:  Global Change Master Directory (GCMD) Instrument Keywords
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                    date:  2023
                    dateType:  (CI_DateTypeCode) revision
                edition:  17
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                    organisationName:  Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)
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                            city:  Greenbelt
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                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/fa0ec8a7-ebed-4f2d-834b-1fa6a1c2e0ed OCEAN > PACIFIC OCEAN > SOUTH PACIFIC OCEAN
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              Anchor:  https://gcmd.earthdata.nasa.gov/kms/concept/b791f381-1c1c-4958-bc7d-b72a15da1174 OCEAN > SOUTHERN OCEAN
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                            description:  Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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            keyword:  Adelaide Island
            keyword:  Ryder Bay
            keyword:  West Antarctic Peninsula
            type:  (MD_KeywordTypeCode) place
            thesaurusName:  (CI_Citation)
                title:  Provider Geographic Names
                date: (inapplicable)
        resourceConstraints:  (MD_Constraints)
            useLimitation:  accessLevel: Public
        resourceConstraints:  (MD_LegalConstraints)
            useConstraints:  (MD_RestrictionCode) otherRestrictions
            otherConstraints:  Cite as: Bakker, Dorothee C. E.; Legge, Oliver J.; Venables, Hugh J. (2017). Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from unknown platforms in the South Pacific Ocean and Southern Oceans from 2010-12-28 to 2014-02-21 (NCEI Accession 0160574). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.tsm_ryder_bay_67s_68w. Accessed [date].
        resourceConstraints:  (MD_LegalConstraints)
            useLimitation:  Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.
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            otherConstraints:  Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
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                title:  Bakker, D.C.E., O.J. Legge, and H.J. Venables (2017). The time-series measurements of carbonate system and other parameters in Ryder Bay, West Antarctic Peninsula during 2012-2014. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee, TSM_Ryder_Bay_67S_68W_2010_2014.
                date:  (CI_Date)
                    date:  2017
                    dateType:  (CI_DateTypeCode) publication
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                    code:  TSM_Ryder_Bay_67S_68W_2010_2014
                citedResponsibleParty:  (CI_ResponsibleParty)
                    individualName:  Bakker, D.C.E., O.J. Legge, and H.J. Venables
                    role:  (CI_RoleCode) author
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                    organisationName:
                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
                    contactInfo:  (CI_Contact)
                        onlineResource:  (CI_OnlineResource)
                            linkage: http://cdiac.ornl.gov
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                            name:  Carbon Dioxide Information Analysis Center website
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                    name:  Ocean CO2
                otherCitationDetails:  [retrieved from http://cdiac.esd.ornl.gov/ftp/oceans/Moorings/Ryder_Bay_67S_68W/]
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                title:  Please cite: Legge, O.J., Bakker, D.C.E., Meredith, M.P., Venables, H.J., Brown, P.J., Jones, E.M., Johnson, M.T. (2016) The seasonal cycle of carbonate system processes in Ryder Bay, West Antarctic Peninsula. Deep-Sea Research II, https://doi.org/10.1016/j.dsr2.2016.11.006
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                    date:  2017-05
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                    code: https://doi.org/10.1016/j.dsr2.2016.11.006
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                            linkage: https://doi.org/10.1016/j.dsr2.2016.11.006
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                    individualName:  Legge, Oliver J.
                    role:  (CI_RoleCode) author
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                    individualName:  Bakker, Dorothee C.E.
                    role:  (CI_RoleCode) author
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                    individualName:  Meredith, Michael P.
                    role:  (CI_RoleCode) author
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                    individualName:  Venables, Hugh J.
                    role:  (CI_RoleCode) author
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                    individualName:  Brown, Peter J.
                    role:  (CI_RoleCode) author
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                    individualName:  Jones, Elizabeth M.
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                    individualName:  Johnson, Martin T.
                    role:  (CI_RoleCode) author
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                    organisationName:  Elsevier BV
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                    name:  Deep Sea Research Part II: Topical Studies in Oceanography
                    issueIdentification:  139
                otherCitationDetails:  ISSN 0967-0645, pp. 167-180
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                title:  NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
                date:  (CI_Date)
                    date:  2022-04
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                    positionName: (unknown)
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                            linkage: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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                            description:  OCADS website
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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                      Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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                otherCitationDetails:  [accessed 2024-02-08]
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        language:
          LanguageCode:  eng; USA
        characterSet:  (MD_CharacterSetCode) utf8
        topicCategory:  (MD_TopicCategoryCode) environment
        topicCategory:  (MD_TopicCategoryCode) oceans
        extent:  (EX_Extent)
            geographicElement:  (EX_GeographicBoundingBox)
                westBoundLongitude:  -68.225
                eastBoundLongitude:  -68.133
                southBoundLatitude:  -67.581
                northBoundLatitude:  -67.57
            temporalElement:  (EX_TemporalExtent)
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                  TimePeriod:
                    beginPosition:  2010-12-28
                    endPosition:  2014-02-21
        supplementalInformation:  These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI.
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                  Anchor:  https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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                        voice:  +1-301-713-3277
                    address:  (CI_Address)
                        electronicMailAddress:  NCEI.Info@noaa.gov
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                fees:  In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
                orderingInstructions:  Contact NCEI for other distribution options and instructions.
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                    linkage: https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0160574.html
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                    linkage: https://doi.org/10.3334/cdiac/otg.tsm_ryder_bay_67s_68w
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                    linkage: https://www.ncei.noaa.gov/archive/accession/oas/160574
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                    linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0105/0160574/
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                    description:  These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
                    function:  (CI_OnLineFunctionCode) download
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    dataQualityInfo:  (DQ_DataQuality)
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                description:  NCEI Accession 0160574 v1.1 was published.
                dateTime:
                  DateTime:  2017-02-22T19:49:09Z
                output:  (LE_Source)
                    sourceCitation:  (CI_Citation)
                        title:  NCEI Accession 0160574 v1.1
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                                onlineResource:  (CI_OnlineResource)
                                    linkage: https://www.ncei.noaa.gov/archive/accession/0160574/1.1
                                    protocol:  HTTPS
                                    name:  NCEI Accession 0160574 v1.1
                                    description:  published 2017-02-22T19:49:09Z
                                    function:  (CI_OnLineFunctionCode) download
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    dataQualityInfo:  (DQ_DataQuality)
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        lineage:  (LI_Lineage)
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: DIC; Unit: μmol/kg; Observation type: time series; Measured or calculated: measured; Sampling instrument: Niskin Bottle; Analyzing instrument: VINDTA and coulometer; Detailed sampling and analyzing information: Unfiltered samples drawn from Niskin bottle using silicon tubing. Poisoned with mercuric chloride. Sealed with greased stopper. Cool, dark storage. Analysed by Coulometry. Samples analysed in three batches, corresponding to three field seasons (2011-2012, 2012-2013, 2013-2014). Samples analysed on two VINDTAs (V4 and V7).; Replicate information: Replicate analyses (separate bottles) for almost all samples; Standardization description: CRM batch 107; Standardization frequency: Two or three CRMs per coulometer cell; CRM manufacturer: Andrew Dickson's lab at Scripps Institution of Oceanography; CRM batch number: 107; Preservation method: mercuric chloride; Preservative volume: 50uL for 250mL samples, 100uL for 500mL; Preservative correction: volume correction applied for poison; Uncertainty: The standard deviation of CRM measurements over the course of each analysis period is consistently less than 2.5 μmol/kg. There is greater variation in replicate precision between the three field seasons. DIC replicate (separate bottles) standard deviation in 2010-2012 was 4.3 μmol kg-1. In 2012-2013 it was 6.2 μmol kg-1 and in 2013-2014 it was 3.4 μmol kg-1.; Quality flag convention: 2 = good, 3 = suspect, 6 = mean of replicates; Method reference: Legge, O.J., Bakker, D.C.E., Meredith, M.P., Venables, H.J., Brown, P.J., Jones, E.M., Johnson, M.T. (2016) The seasonal cycle of carbonate system processes in Ryder Bay, West Antarctic Peninsula. Deep-Sea Research II, https://doi.org/10.1016/j.dsr2.2016.11.006.; Researcher name: Replicate analyses (separate bottles) for almost all samples; Researcher institution: University of East Anglia.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total alkalinity; Abbreviation: TA; Unit: μmol/kg; Observation type: time series; Measured or calculated: measured; Calculation method and parameters:; Sampling instrument: Niskin bottle; Analyzing instrument: VINDTA; Type of titration: Potentiometric, using Metrohm Titrino and VINDTA instruments V7 and V4, calculation of TA using Matlab code by Steven van Heuven, version v33, based on code by Ernie Lewis in QB (1996).; Cell type (open or closed): open; Curve fitting method: Iterative Gran followed by iterative chi-squared; Detailed sampling and analyzing information: Unfiltered samples drawn from Niskin bottle using silicon tubing. Poisoned with mercuric chloride. Sealed with greased stopper. Cool, dark storage. Samples analysed in three batches, corresponding to three field seasons (2011-2012, 2012-2013, 2013-2014). Samples analysed on two VINDTAs (V4 and V7).; Replicate information: Replicate analyses (separate bottles) for almost all samples; Standardization description: CRM batch 107; Standardization frequency: Two or three CRMs per coulometer cell; CRM manufacturer: Andrew Dickson's lab at Scripps Institution of Oceanography; CRM batch number: 107; Preservation method: mercuric chloride; Preservative volume: 50uL for 250mL samples, 100uL for 500mL; Preservative correction: volume correction applied for poison; Uncertainty: The standard deviation of CRM measurements over the course of each analysis period is consistently less than 1.5 μmol/kg. There is greater variation in replicate precision between the three field seasons. TA replicate (separate bottles) standard deviation in 2010-2012 was 4.9 μmol kg-1. In 2012-2013 it was 7.0 μmol kg-1 and in 2013-2014 it was 1.5 μmol kg-1.; Quality flag convention: 2 = good, 3 = suspect, 6 = mean of replicates; Method reference: Legge, O.J., Bakker, D.C.E., Meredith, M.P., Venables, H.J., Brown, P.J., Jones, E.M., Johnson, M.T. (2016) The seasonal cycle of carbonate system processes in Ryder Bay, West Antarctic Peninsula. Deep-Sea Research II, https://doi.org/10.1016/j.dsr2.2016.11.006; Researcher name: Dorothee Bakker and Oliver Legge; Researcher institution: University of East Anglia.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: in-situ temperature; Abbreviation: Temperature; Unit: degrees celcius; Analyzing instrument: SeaBird 19+CTD; Uncertainty: 0.002 degrees celcius; Researcher name: Hugh Venable; Researcher institution: BAS.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Salinity; Abbreviation: Salinity; Unit: PSS; Analyzing instrument: SeaBird 19+ CTD; Uncertainty: 0.005; Researcher name: Hugh Venables; Researcher institution: BAS.
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Total oxidised nitrogen (NOx); Abbreviation: Nitrate; Unit: μmol/kg; Sampling instrument: Niskin Bottle; Uncertainty: 1.50%; Researcher name: Ocean Scientific International Ltd. (OSIL) for Hugh Venables at the British Antarctic Survey (BAS).
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Phosphate; Abbreviation: Phosphate; Unit: μmol/kg; Sampling instrument: Niskin Bottle; Uncertainty: 2.70%; Researcher name: Ocean Scientific International Ltd. (OSIL) for Hugh Venables at the British Antarctic Survey (BAS).
            processStep:  (LE_ProcessStep)
                description:  Parameter or Variable: Silicate; Abbreviation: Silicate; Unit: μmol/kg; Sampling instrument: Niskin Bottle; Uncertainty: 2.60%; Researcher name: Ocean Scientific International Ltd. (OSIL) for Hugh Venables at the British Antarctic Survey (BAS) .
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    metadataMaintenance:  (MD_MaintenanceInformation)
        maintenanceAndUpdateFrequency:  (MD_MaintenanceFrequencyCode) asNeeded
        maintenanceNote:  Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
        contact:  (CI_ResponsibleParty)
            organisationName:  NOAA National Centers for Environmental Information
            role:  (CI_RoleCode) custodian
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    acquisitionInformation:  (MI_AcquisitionInformation)
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  bottle
            type:  bottle
            description:  any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  coulometer for DIC measurement
            type:  coulometer for DIC measurement
            description:  measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  CTD
            type:  CTD
            description:  Conductivity-Temperature-Depth probe
        instrument:  (MI_Instrument)
            identifier:  (MD_Identifier)
                code:  titrator
            type:  titrator
            description:  titrator