Dissolved inorganic carbon (DIC), total alkalinity, pH on total scale, dissolved organic carbon (DOC), chlorofluorocarbons (CFC-11, CFC-12), temperature, salinity and other hydrographic and chemical variables collected from discrete samples and profile observations during NOAA Ship Ronald H. Brown cruise along the GO-SHIP Section P16N_2015, Legs 1 and 2 (EXPOCODEs 33RO20150410 and 33RO20150525) in the Pacific Ocean, from 2015-04-10 to 2015-06-27 (NCEI Accession 0163182)
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title: Dissolved inorganic carbon (DIC), total alkalinity, pH on total scale, dissolved organic carbon (DOC), chlorofluorocarbons (CFC-11, CFC-12), temperature, salinity and other hydrographic and chemical variables collected from discrete samples and profile observations during NOAA Ship Ronald H. Brown cruise along the GO-SHIP Section P16N_2015, Legs 1 and 2 (EXPOCODEs 33RO20150410 and 33RO20150525) in the Pacific Ocean, from 2015-04-10 to 2015-06-27 (NCEI Accession 0163182)
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abstract: This dataset includes discrete and profile observation data collected from NOAA Ship Ronald H. Brown in the Pacific Ocean from 2015-04-10 to 2015-06-27. These data include water temperature, salinity, nutrients, chlorofluorocarbons (CFC-11, CFC-12), sulfur hexafluoride (SF6), dissolved inorganic carbon (DIC), total alkalinity, pH on total scale, dissolved organic carbon (DOC), tritium, helium, delta C14, and delta C13. The International GO-SHIP Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
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description: NCEI Accession 0163182 was revised and v4.4 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2018-07-27T18:56:09Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0163182 v4.4
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0163182/4.4
protocol: HTTPS
name: NCEI Accession 0163182 v4.4
description: published 2018-07-27T18:56:09Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0163182 was revised and v5.5 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2018-10-03T18:56:18Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0163182 v5.5
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0163182/5.5
protocol: HTTPS
name: NCEI Accession 0163182 v5.5
description: published 2018-10-03T18:56:18Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0163182 was revised and v6.6 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2018-10-19T21:16:22Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0163182 v6.6
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0163182/6.6
protocol: HTTPS
name: NCEI Accession 0163182 v6.6
description: published 2018-10-19T21:16:22Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0163182 was revised and v7.7 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2019-02-01T19:18:16Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0163182 v7.7
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0163182/7.7
protocol: HTTPS
name: NCEI Accession 0163182 v7.7
description: published 2019-02-01T19:18:16Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0163182 was revised and v8.8 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2019-08-09T20:04:21Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0163182 v8.8
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0163182/8.8
protocol: HTTPS
name: NCEI Accession 0163182 v8.8
description: published 2019-08-09T20:04:21Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0163182 was revised and v9.9 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2020-05-20T20:44:34Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0163182 v9.9
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0163182/9.9
protocol: HTTPS
name: NCEI Accession 0163182 v9.9
description: published 2020-05-20T20:44:34Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: 568 replicate sample analysis made. Average difference from the mean was 0.70. No systematic differences between the replicates were observed. DICE 1: 0.64 DICE 2: 0.75; Standardization description: The stability of each coulometer cell solution was confirmed three different ways. 1) Gas loops were run at the beginning and end of each cell; 2) CRM’s supplied by Dr. A. Dickson of SIO, were measured near the beginning; and 3) Duplicate samples were typically run throughout the life of the cell solution. Each coulometer was calibrated by injecting aliquots of pure CO2 (99.999%) by means of an 8-port valve (Wilke et al., 1993) outfitted with two calibrated sample loops of different sizes (~1ml and ~2ml). The instruments were each separately calibrated at the beginning of each cell with a minimum of two sets of these gas loop injections and then again at the end of each cell to ensure no drift during the life of the cell. These standard loops were consistent throughout the cruise.; CRM batch number: 143: Certified Value = 2017.75 µmol/kg.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: two-stage open cell acidimetric, potentiometric; Cell type (open or closed): jacketed glass beaker, temperature-controlled; Curve fitting method: Non-linear least squares based on data from pH range 3.5 to 3.0; TA blank correction: N/A; Uncertainty: Reproducibility of B143 analyses: Leg 1 - 1.14 µmol/kg; Leg 2 - 1.10 µmol/kg Repeatability (based on duplicate analyses): Leg 1 - 0.78 µmol/kg; Leg 2 - 0.92 µmol/kg Estimated uncertainty (~68% confidence): 1.8 µmol/kg (includes estimate of CRM uncertainty (1 µmol/kg); mean deviation from CRM certified value (<1 mol/kg); and analysis precision (see above).; Method reference: Dickson, Andrew G., Chris Sabine and James R. Christian, editors, "Guide to Best Practices for Ocean CO2 Measurements", Pices Special Publication 3, IOCCP Report No. 8, October 2007, SOP 3b, "Determination of total alkalinity in sea water using an open-cell titration".
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH; pH scale: total hydrogen ion concentration scale (mol/kg-sw); Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25 °C; Detailed sampling and analyzing information: spectrophotometric determination using purified meta-cresol purple indicator dye; Uncertainty: Reproducibility of B143 analyses: Leg 1 - 0.0012; Leg 2 - 0.0018 (difference reflects inexperience of analyst on Leg 2) Repeatability (based on duplicate analyses): ~0.0005 Estimated uncertainty (~68% confidence): in range 0.006 < Uc < 0.01; the reason for this is that there is no good information about the uncertainty of the Liu et al. calibration (though I do know reasons that cause it to be larger than one might wish, due to the problem of assigning a good "pH" to the Tris buffer used in their calibration approach..
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SF6; Abbreviation: SF6; Unit: FMOL/KG; Controlled vocabulary name: Sulfur Hexaflouride (SF6); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_TOT; Abbreviation: PH_TOT; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_TMP; Abbreviation: PH_TMP; Unit: DEG_C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: N2O; Abbreviation: N2O; Unit: NMOL/KG; Controlled vocabulary name: nitrous oxide (N2O); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: THETA; Abbreviation: THETA; Unit: DEG_C; Controlled vocabulary name: Potential temperature (theta); In-situ / Manipulation / Response variable: in-situ .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0163182 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
platform: (MI_Platform)
identifier: (MD_Identifier)
code: NOAA Ship Ronald H. Brown
description: Updated information from ICES for UNITED STATES platform Ronald H. Brown Flag : UNITED STATES - US (ISO Country Code) Call Sign : WTEC Title : NOAA Ship Platform Class : Research vessel IMO : 9105786 Pennant : R 104 Commissioned Date : 1997-07-19 Current Length : 83.5 Built : 1997 Information Source : http://www.moc.noaa.gov/rb/index.html (URL) Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=277516 *General Comments:* Name RESEARCHER II planned during build was never used.
instrument: (missing)
