Processing Steps |
- Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: TCARBN; Unit: µmol/kg; Observation type: time-series (discrete sampling at MAPCO2 sites); Measured or calculated: Measured; Calculation method and parameters: not calculated; Sampling instrument: 500 ml borosilicate bottles, collected by hand; Analyzing instrument: Jan 2016- August 2018: Mariana Vinta 3D; Since September 2018: Apollo AS-C3 DIC Analyzer and LI-COR LI-7000 CO2 Analyzer; Detailed sampling and analyzing information: Sampling procedure: Bottle rinsed 3 times with seawater, sample taken 20 cm below the surface, a headspace of 20-25 ml is left, sample is spiked with HgCl2, and bottles are sealed with apiezon grease and secured with rubber bands and plastic clamps. Analysis procedure Jan 2016 - August 2018: Sample is placed in waterbath at 20 degrees celcius, before sample analysis, junk seawater samples and blanks are measured until the instrument is stable, then a CRM is measured. All bottles are measured in duplicate, and a triplicate is added if the difference between duplicates is more than 3µmol/kg. Every 3 sample bottles (usually after 6 runs), a CRM is measured to check for stability of the instrument. DIC samples for CRIMP-2 between 06/02/16 and 3/12/17 were measured at SIO using a default salinity of 35. For all other DIC samples, buoy or conductivity probe measurements were used to determine salinity. Analysis procedure since September 2018: Before sample analysis, junk seawater samples were measured until the instrument was stable, then a calibration curve was run using the reference value in µmol/L (calculated from reported CRM salinty and temperaure in the bottle at the time of analysis, measured with a hand-held Fluke 51 II thermometer). All samples were run 4-5 times with 0.75mL volume, until three repeats were <0.05% apart. Every three sample bottles, a CRM was run, and the instrument was recalibrated approximately every 4 hours. Density was calculated using sample salinity from the buoy measurement at the time of sampling when available, and using salinity measured with a VanEssen CTD Diver in the laboratory otherwise; and using temperature of the bottle at the time of analysis measured with a hand-held Fluke 51 II thermometer as well.; Replicate information: Single samples collected, duplicates or triplicates run from the same bottle.; Standardization description: Jan 2016-August 2018: Batch correction with CRMs. Since September 2018: Back-calculation of acid concentration using the reported CRM value as a “True value” with a standardization curve at three different concentrations (built-in standardization function in LabView program).; Standardization frequency: CRM run every three sample bottles. Since September 2018: CRM run every three sample bottles; Restandardization every 4 hours.; CRM manufacturer: Andrew Dickson's lab at Scripps Institute of Oceanography; CRM batch number: 161, 162, 175, 179, 197, 198, 201; Preservation method: HgCl2 saturated solution; Preservative volume: 200 µL mercury chloride added to 500 mL sample; Preservative correction: no poisoning correction applied; Uncertainty: Jan 2016- August 2018: 2 µmol/kg; 2019: 3.0 µmol/kg; 2020: 1.8 µmol/kg; 2021: 1.4 µmol/kg, 2022: 3.2 µmol/kg; 2023: 4.4 µmol/kg; Quality flag convention: 2: good data, 3: questionable data or climatological salinity values, 4: bad data; Method reference: Used coulometric method (2016-2018) and infrared detection method (since Sept 2018) from Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.; Researcher name: Jan 2016- May 2019: Eric DeCarlo; Since May 2019: Christopher Sabine; Researcher institution: University of Hawaii at Manoa.
- Parameter or Variable: Total alkalinity; Abbreviation: ALKALI; Unit: µmol/kg; Observation type: time-series (discrete sampling at MAPCO2 sites); Measured or calculated: Measured; Calculation method and parameters: not calculated; Sampling instrument: 500 ml borosilicate bottles, collected by hand; Analyzing instrument: Jan 2016 - August 2018: Metrohm Titrando 905 alkalinity titrator; Since September 2018: Metrohm 875 Dosimat plus alkalinity titrator; Type of titration: potentiometric titration; Cell type (open or closed): Open; Curve fitting method: Jan 2016 - August 2018: modified Gran approach; Since September 2018: non-linear least squares (NLLS); Detailed sampling and analyzing information: Sampling Procedure: bottle rinsed 3 times with seawater, sample taken 20 cm below the surface, a headspace of 20-25 ml is left, sample is spiked with HgCl2, and bottles are sealed with apiezon grease and secured with rubber bands and plastic clamps. Analysis procedure Jan 2016 - August 2018: The sample is placed in temperature controlled bath at 25 celcius, then approximately 80 grams of sample is weighed and titrated with 0.1 N HCl in 35 g/L NaCl solution. The electrode is calibrated prior to analyses, and only a slope >99% is accepted. All bottles are measured in duplicate, and a triplicate is added if the difference between duplicates is >3µmol/kg. Analysis Procedure since September 2018: The sample is placed in temperature controlled bath at 20 celcius, then approximately 100 grams of sample is weighed and titrated in a 20-point titration with certified ~0.1 N HCl in 35 g/L NaCl solution. All bottles are measured in duplicate, and a triplicate is added if the difference between duplicates is >3µmol/kg.; Replicate information: Single samples collected, duplicates or triplicates run from the same bottle.; Standardization description: Jan 2016-August 2018: Back-calculation of acid concentration using the reported CRM value as a “True value”. Since September 2018: CRMs only as check standards to track performance and calculate uncertainty, no standardization needed with Dosimat calibration, certified acid, and .; Standardization frequency: CRM run every three sample bottles.; CRM manufacturer: Andrew Dickson's lab at Scripps Institute of Oceanography; CRM batch number: 161, 162, 173, 179, 197, 198, 201; Preservation method: HgCl2 saturated solution; Preservative volume: 200 µL mercury chloride added to 500 mL sample; Preservative correction: no correction.; TA blank correction: no correction.; Uncertainty: Jan 2016 - September 2019: 3 µmol/kg; 2020: 2.1 umol/kg; 2023: 4.5 µmol/kg; Quality flag convention: 2: good data, 3: questionable data, 4: bad data; Method reference: Used method from Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp.; Researcher name: Jan 2016 - August 2018: Eric DeCarlo; Since September 2018: Christopher Sabine; Researcher institution: University of Hawaii at Manoa.
- Parameter or Variable: Salinity; Abbreviation: CTDSAL; Unit: on Practical Salinity Scale; Observation type: time-series (discrete sampling and moored instrumentation at MAPCO2 sites); Sampling instrument: Moored SBE 16V2 or SBE 37, Since September 2018: VanEssen CTD Diver when moored sensor wasn't available.; Uncertainty: 0.05 (SBE), or 1% of conductivity value (CTD Diver); Quality flag convention: 2: good data, 3: questionable data/VanEssen CTD Diver, 4: bad data.
- Parameter or Variable: Sea surface temperature; Abbreviation: CTDTMP; Unit: Degrees Celsius; Observation type: time-series (moored instrumentation at MAPCO2 sites); Sampling instrument: SBE 16V2 or SBE 37.
- Parameter or Variable: Total Nitrogen; Abbreviation: TOTAL_NITROGEN_UMOL_L; Unit: UMOL_L.
- Parameter or Variable: Total phosphorous in µmol/L; Abbreviation: TOTAL_PHOSPHOROUS_UMOL_L; Unit: UMOL_L.
- Parameter or Variable: Phosphate in µmol/L; Abbreviation: PHOSPHATE_UMOL_L; Unit: UMOL_L.
- Parameter or Variable: Silicate in µmol/L; Abbreviation: SILICATE_UMOL_L; Unit: UMOL_L.
- Parameter or Variable: Nitrate and nitrite in µmol/L; Abbreviation: NITRATE_NITRITE_UMOL_L; Unit: UMOL_L.
- Parameter or Variable: Ammonia in µmol/L; Abbreviation: AMMONIA_UMOL_L; Unit: UMOL_L.
- Parameter or Variable: Chlorophyll-a in mg/m^3; Abbreviation: CHLA_MG_M3; Unit: mg/m^3 .
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